DP382-N_AUSALLR_MFL48000402

3/28/08

4:35 PM

Page 1

ENGLISH
For service/ support Call: Toll Free Number

1-800-243-0000

(http://us.lgservice.com)
Copyright 2008, LG Electronics U.S.A., Inc.

P/NO : MFL48000402

Page 2

Safety Precaution

CAUTION
RISK OF ELECTRIC SHOCK DO NOT OPEN
CAUTION: TO REDUCE THE RISK OF ELECTRIC SHOCK. DO NOT REMOVE COVER (OR BACK). NO USER-SERVICEABLE PARTS INSIDE. REFER SERVICING TO QUALIFIED SERVICE PERSONNEL. This lightning flash with arrowhead symbol within an equilateral triangle is intended to alert the user to the presence of uninsulated dangerous voltage within the products enclosure that may be of sufficient magnitude to constitute a risk of electric shock to persons. The exclamation point within an equilateral triangle is intended to alert the user to the presence of important operating and maintenance (servicing) instructions in the literature accompanying the product. WARNING: TO PREVENT FIRE OR ELECTRIC SHOCK HAZARD, DO NOT EXPOSE THIS PRODUCT TO RAIN OR MOISTURE. WARNING: Do not install this equipment in a confined space such as a book case or similar unit. CAUTION: Do not block any ventilation openings. Install in accordance with the manufacturer's instructions. Slots and openings in the cabinet are provided for ventilation and to ensure reliable operation of the product and to protect it from over heating. The openings should be never be blocked by placing the product on a bed, sofa, rug or other similar surface. This product should not be placed in a built-in installation such as a bookcase or rack unless proper ventilation is provided or the manufacturer's instruction has been adhered to. CAUTION: This product employs a Laser System. To ensure proper use of this product, please read this owners manual carefully and retain it for future reference. Should the unit require maintenance, contact an authorized service center. Use of controls, adjustments or the performance of procedures other than those specified herein may result in hazardous radiation exposure. To prevent direct exposure to laser beam, do not try to open the enclosure. Visible laser radiation when open. DO NOT STARE INTO BEAM. CAUTION: The apparatus should not be exposed to water (dripping or splashing) and no objects filled with liquids, such as vases, should be placed on the apparatus.
CAUTION The ventilation should not be impeded by covering the ventilation openings with items, such as newspapers, table-cloth, curtains etc. No naked flame sources, such as lighted candles, should be placed on the apparatus. Used batteries should be disposed of safely and not incinerated. Attention should be shown to the environment aspects of battery disposal. Use the apparatus in moderate climates only. The excessive sound pressure from earphones and headphones can cause hearing loss. The battery shall not be exposed to excessive heat such as sunshine, fire or the like.
CAUTION concerning the Power Cord Most appliances recommend they be placed upon a dedicated circuit; That is, a single outlet circuit which powers only that appliance and has no additional outlets or branch circuits. Check the specification page of this owner's manual to be certain.Do not overload wall outlets. Overloaded wall outlets, loose or damaged wall outlets, extension cords, frayed power cords, or damaged or cracked wire insulation are dangerous. Any of these conditions could result in electric shock or fire. Periodically examine the cord of your appliance, and if its appearance indicates damage or deterioration, unplug it, discontinue use of the appliance, and have the cord replaced with an exact replacement part by an authorized service center. Protect the power cord from physical or mechanical abuse, such as being twisted, kinked, pinched, closed in a door, or walked upon. Pay particular attention to plugs, wall outlets, and the point where the cord exits the appliance. To disconnect power from the mains, pull out the mains cord plug. When installing the product, ensure that the plug is easily accessible.
F g e a r R T C T in c d n H in v o t

F M 1 P

Page 3
FCC WARNING: This equipment may generate or use radio frequency energy. Changes or modifications to this equipment may cause harmful interference unless the modifications are expressly approved in the instruction manual. The user could lose the authority to operate this equipment if an unauthorized change or modification is made. REGULATORY INFORMATION: FCC Part 15 This equipment has been tested and found to comply with the limits for a Class B digital device, pursuant to Part 15 of the FCC Rules. These limits are designed to provide reasonable protection against harmful interference in a residential installation. This equipment generates, uses and can radiate radio frequency energy and, if not installed and used in accordance with the instructions, may cause harmful interference to radio communications. However, there is no guarantee that interference will not occur in a particular installation. If this equipment does cause harmful interference to radio or television reception, which can be determined by turning the equipment off and on, the user is encouraged to try to correct the interference by one or more of the following measures: Reorient or relocate the receiving antenna. Increase the separation between the equipment and receiver. Connect the equipment into an outlet on a circuit different from that to which the receiver is connected. Consult the dealer or an experienced radio/TV technician for help. FCC COMPLIANCE: The responsible party for this products compliance is: Marketed and Distributed by LG Electronics U.S.A., Inc., 1000 Sylvan Avenue, Englewood Cliffs, NJ. Phone: 1-201-816-2000.

Important Safety Instructions
1. Read these instructions. 2. Keep these instructions. 3. Heed all warnings. 4. Follow all instructions. 5. Do not use this apparatus near water. 6. Clean only with dry cloth. 7. Do not block any ventilation openings. Install in accordance with the manufacturers instructions. 8. Do not install near any heat sources such as radiators, heat registers, stoves, or other apparatus (including amplifiers) that produce heat. 9. Do not defeat the safety purpose of the polarized or grounding-type plug. A polarized plug has two blades with one wider than the other. A grounding type plug has two blades and a third grounding prong. The wide blade or the third prong are provided for your safety. If the provided plug does not fit into your outlet, consult an electrician for replacement of the obsolete outlet. 10. Protect the power cord from being walked on or pinched particularly at plugs, convenience receptacles, and the point where they exit from the apparatus. 11. Only use attachments/accessories specified by the manufacturer. 12. Use only with the cart, stand, tripod, bracket, or table specified by the manufacturer, or sold with the apparatus. When a cart is used, use caution when moving the cart/apparatus combination to avoid injury from tipover.
13. Unplug this apparatus during lightning storms or when unused for long periods of time. 14. Refer all servicing to qualified service personnel. Servicing is required when the apparatus has been damaged in any way, such as power-supply cord or plug is damaged, liquid has been spilled or objects have fallen into the apparatus, the apparatus has been exposed to rain or moisture, does not operate normally, or has been dropped.

Page 4

Safety Precaution.2-3 Important Safety Instructions.3 Types of Playable Discs.4 Rechargeable battery.4 Main Unit.5 Remote Control.6 Power connections.7 Hooking up the unit.8 Revolving the LCD panel.8 Selecting the operation mode.8 Adjust the settings.9-10 Displaying Disc Information.10 Playing a Disc.11-12 Listening to Music Disc or files.13 Viewing photo files.13 Using a USB Flash Drive.14 Watching a AV input.14 Language Codes / Area Codes.15 Troubleshooting / Specifications.16

About the

Symbol Display
may appear on your TV display during operation and indicates that the function explained in this owners manual is not available on that disc.

Regional Codes

This unit has a regional code printed on the rear of the unit. This unit can play only DVD discs labeled same as the rear of the unit or ALL. Most DVD discs have a globe with one or more numbers in it clearly visible on the cover. This number must match your units regional code or the disc cannot play. If you try to play a DVD with a different regional code from your player, the message Check Regional Code appears on the TV screen.

Contents

Copyrights
It is forbidden by law to copy, broadcast, show, broadcast via cable, play in public, or rent copyrighted material without permission. This product features the copy protection function developed by Macrovision. Copy protection signals are recorded on some discs. When recording and playing the pictures of these discs picture noise will appear. This product incorporates copyright protection technology that is protected by method claims of certain U.S. patents and other intellectual property rights owned by Macrovision Corporation and other rights owners. Use of this copyright protection technology must be authorized by Macrovision Corporation, and is intended for home and other limited viewing uses only unless otherwise authorized by Macrovision Corporation. Reverse engineering or disassembly is prohibited.

Types of Playable Discs

DVD-VIDEO: Discs such as movies that can be purchased or rented. DVD-R: Video mode and finalized only DVD-RW: VR mode, Video mode and finalized only DVD+R: Video mode only DVD+RW: Video mode only Audio CD: Music CDs or CD-R/CD-RW in music CD format that can be purchased. This unit plays DVDR/RW and CD-R/RW that contains audio titles, MP3, WMA and/or JPEG files. Some DVDRW/DVDR or CD-RW/CD-R cannot be played on this unit due to the recording quality or physical condition of the disc, or the characteristics of the recording device and authoring software.

Rechargeable battery

Its internal rechargeable battery provides you with the freedom to pass it around and play the files without the power cord. The internal rechargeable battery will start charging only when the unit is turned off and the AC adapter is connected to a power outlet. The charging stops if you turn on the unit. The charging will take approximately 3 hour 30 minutes. Operating time on battery: approximately 3 hour 30 minutes The operating time on battery may vary depending on the battery status, operational status and environment conditions. The battery indicator will turn red while charging. Once the charging is complete, the indicator light changes to green. When the remaining time of the battery power is under a few minutes, Check Battery Status will appear on the screen.

V o E s

Page 5

Main Unit

a LCD screen b Playback Control Buttons N (Play): Starts playback. x (Stop): Stops playback. X (PAUSE/STEP): Pauses playback temporarily/ press repeatedly for frame-by-frame playback. . (Skip): Search backward* or returns to the beginning of current chapter or track or go to the previous chapter or track. > (Skip): Search forward* or Go to next chapter or track. * Press and hold button for about two seconds. c Speakers d Function Buttons POWER (1): Turn the unit ON or OFF. SETUP: Accesses or exits the setup menu. MENU: Accesses the DVD menu. DISPLAY: Accesses On-Screen Display. LCD MODE: Selects the LCD mode. (16:9, 4:3 or Off) COLOR/BRIGHT*: Displays the Brightness or Color menu for LCD display. MODE: Selects a operation mode among [DISC], [USB] and [AV IN]. * To adjust the color or brightness of the LCD display, press COLOR/BRIGHT repeatedly on the main unit to display the Brightness or Color menu then use b / B to adjust the value. Press ENTER to confirm the adjustment. e Joystick: Use the joystick to select an item in the menu. Press the joystick to confirm the menu selection. f Battery charge and power indicator The indicator turns red in charging and changes to green color when the charging is complete. (Refer to page 4 for details.) The indicator turns green for a few seconds when the unit is turned on. g Disc Lid h OPEN (Z): Opens the disc lid. Volume: You can adjust the volume level using the volume controller on the right side. Earphones: Connect a earphones to the earphones jack on the right side to enjoy the sound individually. i USB Port: Connect a USB Flash Drive. j Remote sensor: Point the remote control here. To control the unit using the remote control, do not fold the LCD panel down.

Page 6

Remote Control
SKIP/SEARCH (. / >): Search* backward / forward. Go to next or previous chapter/track. * Press and hold button for about two seconds. SLOW (t / T): Reverse/ Forward slow playback.
Put the battery into the Remote Control
Pinch the battery holder clip together then pull the tab to remove the battery holder. Insert the battery with the + facing in the same direction as the + on the battery holder. Replace the battery holder with battery into the Remote Control unit making sure that it is fully inserted. Replace Remote Control unit battery with 3V micro lithium cells such as CR. 2025 or its equivalent. Dispose of battery safety in accordance with local laws. Do not dispose of in fire.
SETUP: Accesses or exits the setup menu. MENU: Accesses the DVD menu. vV b B: Navigates the menus. ENTER ( ): Confirms menu selection.
RETURN (O): Press to move backwards in the menu or exit the menu. DISPLAY: Accesses On-Screen Display.
PAUSE/STEP (X): Pauses playback temporarily/ press repeatedly for frame-by-frame playback. PLAY (N): Starts playback. STOP (x): Stops playback. Numerical buttons: Selects numbered options in a menu. Warning for replaceable lithium battery danger of explosion if battery incorrectly replaced. replace only with the same type battery. additional warning marking close to the battery if intended to be replaced by users. *
PROG.: Enters the program edit mode. CLEAR: Removes a track number on the Program List.
TITLE: Access the discs title menu.
POWER (1): Switches the unit ON or OFF. AUDIO ( channel. SUBTITLE ( ANGLE ( available. ): Selects an audio language or audio ): Selects a subtitle language. ): Selects a DVD camera angle, if
REPEAT: Repeats a chapter, track, title or all. A-B: Repeats a section. ZOOM: Enlarges video image. MARKER : Marks any point during playback. SEARCH : Displays [Marker Search] menu. RANDOM: Plays tracks in random order.
Warning : The battery used in this device may present a fire or chemical burn hazard if mistreated. Do not recharge, disassemble, incinerate, or heat above 100 C (212 F). Replace the battery with Matsushita Elec. Ind. Co., Ltd. (Panasonic), part no. CR. 2025 only. Use of another battery may present a risk of fire or explosion. Dispose of used batteries. Keep batteries away from children. Do not disassemble or dispose of in fire.

T 8 c te

Page 7

Power connections

Connecting the Power Cable
Connect the supplied power cable from the unit to a power socket. y Right side of the unit Plug into the cars cigarette lighter socket. v-

Right side of unit

Plug into the DC 9V IN jack.
Plug into a power source.
Automotive adapter This automotive adapter operates on DC 8.5-16V. Contact an electrical parts distributor for assistance in selecting a suitable automotive adapter. Manufactured by GRAND POWER ELECTRONIC TECHNOLOGY (SHENZHEN) CO., LTD. Caution To prevent electrical shock and possible damage to your unit or vehicle, always unplug the automotive adapter from the cigarette lighter socket before you remove the plug from your unit. A 1.5 amp. 250V fuse for protection is installed in the automotive adapter. While the engine is being started, disconnect the automotive adapter from the cars cigarette lighter socket. Do not operate your unit when the car battery is discharged. Peak current from the car generator may cause the DC fuse to blow. If the vehicles supply voltage drops below approximately 10 volts, your unit may not work properly. Do not leave your unit in a place where the temperature exceeds 70C (158F), or the pick-up device may be damaged. Examples include: - Inside a car with the windows closed and in direct sunshine. - Near a heating appliance.
* The actual set may differ from the drawing. AC adapter This AC adapter operates on 100-240V~ 0.5A 50/60Hz. Contact an electrical parts distributor for assistance in selecting a suitable AC plug adapter or AC cord set. Manufactured by I-MAG ELECTRONICS CO., LTD
Connect the Automotive adapter
This unit and its automotive adapter are designed for use in vehicles that have 8.5-16 volt, negative ground electrical systems. This is standard for most vehicles. If your vehicle has a different type of electrical system, the DC power system cannot be used.

Page 8

Hooking up the unit
Audio and Video Connection for AV IN or AV OUT
Connect the AV IN/OUT jack on the unit to the corresponding input or output jacks on your TV or an external device using the supplied AV cable as shown below. Right side of the unit

Revolving the LCD panel

You can revolve the LCD panel of the unit clockwise a maximum of 180 degrees for use. You can also operate the unit after revolving the LCD panel 180 degrees and folding it back down.
To revolve the LCD panel, place the unit on a stable and even surface such as on a table. Push the LCD panel up and then lift it into a vertical position. Revolve the LCD panel clockwise slowly 180 degrees. If you need, fold the LCD panel after revolving it. To revolve the LCD panel to its original position, open the LCD panel to a vertical position. Revolve the LCD panel counterclockwise slowly 180 degrees. When finished using the unit, return the LCD panel to its original position. Do not leave the LCD panel in the face-up position, or sudden shocks may damage it.

T fi la s

TV or the external device
Plug into the AV IN/OUT jack.

M p D M

Manufactured under license from Dolby Laboratories. Dolby and the double-D symbol are trademarks of Dolby Laboratories.
Selecting the operation mode
You need to select a operation mode before using this unit. Press MODE on the unit and the operation mode selection menu appears. Use b / B to select a mode then press ENTER. Select [DISC] to playback the inserted disc. Select [AV IN] to watch a video/audio signals from the external device using this unit. Select [USB] to playback the file(s) in the connected USB Flash Drive.

Page 9

Adjust the settings

BUTTON

1 Display setup menu: 2 Select a desired option on the first level: 3 Move to second level: 4 Select a desired option on the second level: 5 Move to third level: 6 Change the setting: SETUP

vV B vV B v V / ENTER

Adjust the display settings
TV Aspect Select which screen aspect to use based on the shape of your TV screen. [4:3]: Select when a standard 4:3 TV is connected. [16:9]: Select when a 16:9 wide TV is connected. Display Mode If you selected 4:3, youll need to define how you would like widescreen programs and films to be displayed on your TV screen. [LetterBox]: This displays a widescreen picture with black bands at the top and bottom of the screen. [Panscan]: This fills the entire 4:3 screen, cropping the picture as necessary.
Adjust the audio settings
Adjust the settings - more you can do
When you turn on for the first time
The menu for a language selection will appear when you turn on the unit for the first time. You must select a language to use the unit. Use vV b B to select a language then press ENTER and the confirm menu will appear. Use b B to select [Enter] then press ENTER.
DRC (Dynamic Range Control) Make the sound clear when the volume is turned down (Dolby Digital only). Set to [On] for this effect. Vocal Set to [On] only when a multi-channel karaoke DVD is playing. The karaoke channels on the disc, mix into normal stereo sound.
Adjust the language settings
Menu Language Select a language for the Setup menu and on-screen display. Disc Audio/Subtitle/Menu Select a language for the Disc Audio/Subtitle/ Menu. e d s. [Original]: Refers to the original language in which the disc was recorded. [Other]: To select another language, press number buttons then ENTER to enter the corresponding 4-digit number according to the language code list. (see page 15) If you make a mistake while entering number, press CLEAR to delete numbers then correct it. [Off] (for Disc Subtitle): Turn off Subtitle.

Page 10

Adjust the lock settings
You must set the [Area Code] option to use the lock options. Select [Area Code] option then press B. Enter a 4-digit password then press ENTER. Enter it again then press ENTER to verify. If you make a mistake while entering number, press CLEAR then correct it. If you forget your password you can reset it. First, remove the disc in the unit. Display setup menu then input the 6-digit number 210499 and the password will be cleared. Rating Select a rating level. The lower the level, the stricter the rating. Select [Unlock] to deactivate the rating. Password Sets or changes the password for lock settings. [New]: Enter a new 4-digits password using the numerical buttons then press ENTER. Enter the password again to confirm. [Change]: Enter the new password twice after entering the current password. Area Code Select a code for a geographic area as the playback rating level. This determines which areas standards are used to rate DVDs controlled by the parental lock. (See page 15)

Displaying Disc Information
1 Press DISPLAY during playback: 2 Select an item: 3 Adjust the Display menu settings: 4 To return the exit: DISPLAY

vV b B / ENTER

DISPLAY
Displaying Disc Information - more you can do
You can select an item by pressing vV and change or select the setting by pressing b B. Current title number/total number of titles Current chapter number/total number of chapters Elapsed playing time Selected audio language or channel Selected subtitle Selected angle/total number of angles You can check the battery charge status by pressing DISPLAY during playback when the DC 9V IN jack is not connected.

P o p ( (X w

Adjust the others settings
B.L.E. (Black Level Expansion) To select the black level of playback pictures. Set your preference and monitors ability.

Recharge

T (V s m S d
Symbol Used in this Manual
A section whose title has one of the following symbols are applicable only to the disc or file represented by the symbol. ALL ACD All discs and files Audio CDs DVD MP3 DVD and finalized DVDR/RW MP3 files WMA WMA files

Page 11

Playing a Disc
1 Open the disc lid: 2 Insert a Disc: 3 Close the disc lid: 4 Start playback: 5 Adjust the volume: OPEN (Z) N x PLAY STOP VOLUME

Pause a playback

Press PAUSE/STEP (X) to pause playback. Press PLAY ( N) to continue playback.

Frame-by-Frame playback

Press PAUSE/STEP (X) repeatedly to play Frame-by-Frame playback.

Playing repeatedly

6 To stop playback:
Press REPEAT repeatedly to select an item to be repeated. The current title, chapter or track will be played back repeatedly. To return to normal playback, press REPEAT repeatedly to select [Off].
Fast forward or fast reverse
Playing a Disc - more you can do

Stops the playback

Press STOP (x) to stop playback, the unit records the stopped point depending on the disc. Xx appears on the screen briefly. Press PLAY ( N) to resume playback (from the scene point). If you press STOP (x) again or unload the disc ( x appears on the screen), the unit will clear the stopped point. (Xx =Resume Stop, x =Complete Stop) The resume point may be cleared when a button is pressed. (for example: POWER, OPEN, etc) k
Press and hold SKIP (. or >) to play fast forward or fast reverse during playback. You can change the various playback speed by pressing and hold SKIP (. or >) repeatedly. Press PLAY ( N) to continue play at normal speed.
Repeating a specific portion (A-B)
Press A-B at the beginning of the portion you wish to repeat and again at the end of the portion. Your selected portion will be repeated continually. To return to normal playback, press A-B to select [Off].

Playing a DVD that has a menu
Selecting a subtitle language
During playback, press SUBTITLE ( language.
Most DVDs now have menus which load first before the film begins to play. You can navigate these menus using vV b B or number button to highlight an option. Press ENTER to select.
) repeatedly to select a desired subtitle
Watching from a different angle

Playing a DVD VR disc

This unit will play DVD-RW disc that are recorded using the Video Recording (VR) format. When you insert a DVD VR disc, the menu will appear on the screen. Use vV to select a title then press PLAY ( N). To display DVD-VR menu, press MENU or TITLE. Some DVD-VR disc are made with CPRM data by DVD RECORDER. The unit does not support these kinds of discs.
If the angle indicator appears on the screen for a moment, you can select a different camera angle by pressing ANGLE ( ) repeatedly.
Hearing a different audio
During playback, press AUDIO ( ) repeatedly to switch between the available audio languages, channels or encoding methods.
Slow down the playing speed Skip to the next/previous chapter/track
Press SKIP (>) to move to the next chapter/track/file. Press SKIP (.) to return to the beginning of the current chapter/track/file. Press SKIP (.) twice briefly to step back to the previous chapter/track/file.
During playback, press SLOW (t or T) to slow down reverse or forward playback. You can change the various playback speed by pressing SLOW (t or T) repeatedly. Press PLAY ( N) to continue play at normal speed.

Page 12

Watching a enlarged video image

Screen Saver

The screen saver appears when you leave the unit in Stop mode for about five minutes. If the Screen Saver is displayed for five minutes, the unit automatically turns itself off.
During playback or pause mode, press ZOOM repeatedly to select zoom mode. You can move through the zoomed picture using vVb B buttons. Press CLEAR to exit.

Viewing the title menu

Mixed disc or USB Flash Drive MP3/WMA and JPEG
When playing a disc or USB Flash Drive contained with MP3/WMA and JPEG files together, you can select which menu of files you would like to play by pressing TITLE.

Viewing photo files - more you can do
Viewing photo files as a slide show
Use vV b B to highlight ( ) icon then press ENTER to start slide show. You can change slide show speed using b B when ( ) icon is highlighted.
Skip to the next/previous photo
Press SKIP (. or >) to view the previous/next photo.

Rotate a photo

Use vV to rotate the photo in full screen counterclockwise or clockwise while viewing a photo in full screen.

Pause a slide show

Press PAUSE/STEP (X) to pause a slide show. Press PLAY ( N) to continue the slide show.
Displaying file information (ID3 TAG)
While playing a MP3 file containing file information, you can display the information by pressing DISPLAY repeatedly.
Listening to music during slide show
You can listen to music during slide show, if the disc contains music and photo files together. Use vV b B to highlight ( ) icon then press ENTER to start slide show.
MP3/WMA music file requirement
MP3/WMA compatibility with this unit is limited as follows:
Watching an enlarged photo image
While viewing a photo in full screen, press ZOOM repeatedly to select zoom mode. You can move through the zoomed photo using vVb B buttons. Press CLEAR to exit.
File extensions:.mp3,.wma
Sampling frequency: within 8 - 48 kHz (MP3), within 32 - 48kHz (WMA) Bit rate: within 8 - 320kbps (MP3), within 32 - 192kbps (WMA) CD-R/RW, DVDR/RW Format: ISO 9660 Maximum Files/Disc: Less than 650 (total number of files and folders)

Photo file requirement

JPEG file compatibility with this unit is limited as follows: File extensions:.jpg Photo size: Less than 2MB recommended CD-R/RW, DVDR/RW Format: ISO 9660 Maximum Files/Disc: Less than 650 (total number of files and folders)

Page 14

Using a USB Flash Drive
You can play MP3/WMA/JPEG files in the USB Flash Drive with version 1.1.

Watching a AV input

You can watch a video/audio signals from the external device using this unit.

1 Connect a USB Flash Drive to the USB port on the unit: 2 Display the menu to select the USB operation mode: 3 Select [USB]: 3 Select a file: 4 Play the file: 5 Remove the USB Flash Drive: Notes a USB Flash Drive
You can switch among [DISC], [USB] and [AV IN] mode using MODE button. Do not extract the USB device in operation. We recommend that you back up your important files in the USB Flash Drive to protect against accidental loss. If you use a USB extension cable or USB HUB, the USB device might not be recognized. Music files (MP3/WMA) and photo files (JPEG) files can be played. For details of operation on each file type, refer to relevant pages. Maximum Files/USB Flash Drive: Less than 650 (total number of files and folders) The USB function of this unit does not support all kinds of USB devices. Digital camera and mobile phone are not supported.
1 Connect the external device to this unit using the supplied AV cable. (Page 8) 2 Display the menu to select the [AV IN] mode: 3 Select [AV IN]: 4 Watch a video from the external device. 5 To exit [AV IN] mode, select [DISC] or [USB]. MODE b B, ENTER MODE, b B, ENTER
MODE b B, ENTER v V, MENU N PLAY

Page 15

Language Codes
Use this list to input your desired language for the following initial settings: Disc Audio, Disc Subtitle, Disc Menu.
Language Afar Afrikaans Albanian Ameharic Arabic Armenian Assamese Aymara Azerbaijani Bashkir Basque Bengali, Bangla Bhutani Bihari Breton Bulgarian Burmese Byelorussian Chinese Code 9072 Language Croatian Czech Danish Dutch English Esperanto Estonian Faroese Fiji Finnish French Frisian Galician Georgian German Greek Greenlandic Guarani Gujarati Code 7185 Language Hausa Hebrew Hindi Hungarian Icelandic Indonesian Interlingua Irish Italian Javanese Kannada Kashmiri Kazakh Kirghiz Korean Kurdish Laothian Latin Latvian, Lettish Code 7686 Language Lingala Lithuanian Macedonian Malagasy Malay Malayalam Maori Marathi Moldavian Mongolian Nauru Nepali Norwegian Oriya Panjabi Pashto, Pushto Persian Polish Portuguese Code 8084 Language Quechua Rhaeto-Romance Rumanian Russian Samoan Sanskrit Scots Gaelic Serbian Serbo-Croatian Shona Sindhi Singhalese Slovak Slovenian Spanish Sudanese Swahili Swedish Tagalog Code 8476 Language Tajik Tamil Telugu Thai Tonga Turkish Turkmen Twi Ukrainian Urdu Uzbek Vietnamese Volapk Welsh Wolof Xhosa Yiddish Yoruba Zulu Code 9085

Area Codes

Choose a area code from this list.
Area Afghanistan Argentina Australia Austria Belgium Bhutan Bolivia Brazil Cambodia Canada Chile China Colombia Congo Code AF AR AU AT BE BT BO BR KH CA CL CN CO CG Area Costa Rica Croatia Czech Republic Denmark Ecuador Egypt El Salvador Ethiopia Fiji Finland France Germany Great Britain Greece Code CR HR CZ DK EC EG SV ET FJ FI FR DE GB GR Area Greenland Hong Kong Hungary India Indonesia Israel Italy Jamaica Japan Kenya Kuwait Libya Luxembourg Malaysia Code GL HK HU IN ID IL IT JM JP KE KW LY LU MY Area Maldives Mexico Monaco Mongolia Morocco Nepal Netherlands Netherlands Antilles New Zealand Nigeria Norway Oman Pakistan Panama Code MV MX MC MN MA NP NL AN NZ NG NO OM PK PA Area Paraguay Philippines Poland Portugal Romania Russian Federation Saudi Arabia Senegal Singapore Slovak Republic Slovenia South Africa South Korea Spain Code PY PH PL PT RO RU SA SN SG SK SI ZA KR ES Area Sri Lanka Sweden Switzerland Taiwan Thailand Turkey Uganda Ukraine United States Uruguay Uzbekistan Vietnam Zimbabwe Code LK SE CH TW TH TR UG UA US UY UZ VN ZW

WARRANTY PERIOD: LABOR: 90 days from the Date of Purchase. PARTS: One Year from the Date of Purchase. * Parts replaced are warranted for the remaining portion of the original warranty period. HOW SERVICE IS HANDLED: Call 1-800-243-0000 for instructions on getting the defective unit repaired or

replaced.

Please retain dated sales receipt and your box to return the unit to LG for repair or replacement. Shipping both ways will be paid by LG during the Warranty Period. After the Warranty Period, you pay inbound shipping charges and LG pays return shipping charges. Visit our website at: http://us.lgservice.com
THIS WARRANTY IS IN LIEU OF ANY OTHER WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION, ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. TO THE EXTENT ANY IMPLIED WARRANTY IS REQUIRED BY LAW, IT IS LIMITED IN DURATION TO THE EXPRESS WARRANTY PERIOD ABOVE. LG ELECTRONICS WILL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL, INDIRECT, SPECIAL OR PUNITIVE DAMAGES OF ANY NATURE, EVEN IF ADVISED OF THE POSSIBILITY OF SUCH DAMAGES, INCLUDING WITHOUT LIMITATION, LOST REVENUES OR PROFITS, LOST OR CORRUPTED PROGRAMMING OR DATA, OR ANY OTHER DAMAGE WHETHER BASED IN CONTRACT, TORT OR OTHERWISE. Some states do not allow the exclusion or limitation of incidental or consequential damages or limitation on how long an implied warranty lasts, so the above exclusion or limitation may not apply to you. This warranty gives you specific legal rights and you may also have other rights that may vary from state to state. THIS LIMITED WARRANTY DOES NOT APPLY TO: Damages or operating problems that result from shipping, installation, adjustment of user controls, calibration, maintenance or failure to maintain, or separate system components; and Damages or operating problems that result from normal wear and tear, misuse, abuse, operation outside environmental specifications or contrary to the requirements or precautions in the Operating Guide, accident, lightning strikes or other natural causes, unauthorized modification or alteration, incorrect electrical current or voltage, reception problem caused by inadequate home antenna or faulty antenna connections, computer software, institutional or commercial use, or other causes not arising out of defect in material or workmanship. Therefore, the cost of repair or replacement of such defective product shall be borne by the consumer. CUSTOMER INTER-ACTIVE CENTER NUMBERS:

For nearest Authorized Service Center, Where to buy, Product Assistance, or Customer Assistance Call 1-800-243-0000 (24 hours a day, 365 days per year) and select appropriate options from the menu. Or visit our website at http://us.lgservice.com LG ELECTRONICS U.S.A., INC. 1000 SYLVAN AVENUE ENGLEWOOD CLIFFS, NJ Issue O Printed in China

In addition, tank 241-C-108 was vapor sampled in August 1994 in accordance with WHC-SD-WM-DQO-002, Data Quality Objectives for Generic In-T& Health and s@@
Vizpor Issue Resolution, March 7, 1994 (Osborne et al. 1994).1 ksults from this vapor
sampling event are reported in WHC-SD-WM-ER-423, T& 241-C-108 Vapor Sampling and
Analysis Tank Chamcterization Repo?t (Huckaby 1995).2 All gases and vapors of concern
showed concentrations lower than the safety screening limit of 25 percent of the lower flammability limit.
10sborne, J. W., J. L. Huckaby, T. P. Rudolph, E. R, Hewitt, D. D. Mahlum, J. Y. Young, and C. M. Anderson, 1994, Data Quality Objectives for Generic In-T& Heailh and Safety Vapor Issue Resolution, March Z 1994, WHC-SD-WM-DQO-002, Rev. O, Westinghouse Hanford Company, Richland, Washington. 2Huckaby, J. L., 1995, Tank 241-C-108 Vapor S2rmplingand Analysis Tank Characterization Repoti, WHC-SD-WM-ER-423, Rev. 1, Westinghouse Hanford Company, Richland, Washington.
WHC-SD-WM-ER-503, WV. O CONTENTS
1.O INTRODUCTION.1-1 l.l PURPOSE.1-1 1.2 SCOPE.1-1 2.0 HISTORICAL TANK INFORMATION. 2.1 TANK STATUS. 2.2 TANK DESIGN AND BACKGROUND. 2.3 PROCESS KNOWLEDGE. 2.3.1 Waste Transfer History. 2.3.2 Historical EstimationofTank Contents 2.4 SURVEILLANCE DATA. 2.4.1 Surface-Level Readings. 2.4.21nternal TankTernperatures. 2.4.3 DyWell Surveillance. 2.4.4 Tank Ztl-C-108 Photographs. 2-1.2-1.2-1.2-2.2-2.2-6.2-9.2-9.2-10.2-13. 2-13.3-1. 3-1.3-2. 3-7
3.OTANK SAMPLING OVERVIEW. 3.1 DESCRIPTION OF CORE AND AUGER SAMPLING EVENTS (1994) 3.1.1 Sample Handling. 3.2 DESCRIPTION OF VAPOR SAMPLING EVENT (1994). 4.0 ANALYTICAL RESULTS. 4.1 OVERVIEW. 4.2 TOTAL ALPHA. 4.3 THERMODYNAMIC ANALYSES. 4.3.1 TGA. 4.3.2 DSC. 4.4 ICE. 4.5 ANIONS. 4.6 RADIOCHEMICAL. 4.7 TOTAL CARBON. 4.8 INORGANIC GASES AND VAPORS. 4.8.1 Ammonia, Hydrogen, andNitrousOxide. 4.8.2 Carbon Dioxide and Carbon Monoxide. 4.8.3 Nitric Oxide, Nitrogen Dioxide, Wa*r and Tritium 4.9 ORG~CVNOW. 4.9.1 Positively Identifkd Organic Analytes. 4.9.2 Tentatively Identified Organic Analytes. 4.9.3 Total Nonmethane OrgardcCornpou@. 4.9.4 Discussion of Organic Anal~.
.4-1.4-1.4-3.4-3.4-3.4-5.4-5.4-9.4-11.414.4-15. 4-16. 4-17. 4-17. +18. 4-18. 4-20. 4-21.4-25
WHC-SD-WM-ER-503, kf. CONTENTS (continued)
5.0 INTERPRETATION OF CHARACTERIZATION RESULTS. 5.1 ASSESSMENT OF SAMPLING AND ANALYTICAL RESULTS 5.1.1 Field Observations. 5ol.2Quality Control Assessment. 5.1.3 Data Consistency Checks. 5.2 COMPARISON OF RESULTS FROM DIFFHU3W SAMPLING EvENTs. 5.3 TANK WASTE PROFILE. 5.4 COMPARISON OF TR4NSFER HISTORY AND ANALYTICAL INFORMATION. 5.5 EVALUATION OF PROGRAM REQUIREMENTS. 5.5.1 Safety Evaluation.

. 5-1. 5-1.5-1.5-1.5-3

.5-7.5-8.5-9.5-9.5-9
6.0 CONCLUSIONS AND RECOMMENDATIONS.6-1 7.0 REFERENCES.7-1 8.0 BIBLIOGRAPHY.8-1 APPENDIXES A B c TANK 241-C-108 ANALYTICAL METHODS AND PROCEDURES. A-1 TANK 241-C-108 ANALYTICAL DATA RESULTS. B-1 TANK 241-C-108 SELECTED THERMOGRAVIMETRIC AND DIFFERENTML SCANNING CALORIMETRY GRAPHS. LIST OF FIGURES Tanlc241-C-108 Riser Location. Tank241-C-108 Cross-Section. Tank 241-C-108 Level History. Tank 241-C-108 Tank Layer Model.. Tank 241-C-108 Weekly High Temperature Plot. Auger Sampling Procedure for Riser7. Sample Auger Breakdown and Compositing Pmcdure Flowchart for Data Collection and Preparation.. 2-4. 2-5. 2-8.2-10. 2-14. 3-5.3-8. 3-12 C-1

WHC-SD-WM-ER-503, R(N. O

This page intentiomlly left blank.
WHC-SD-WM-ER-503, ~V. O TANK CHARACTERIZATION REPORT FOR SINGLE-SHELL TANK 241-C-108

1.0 INTRODUCTION

This Tank Characterization Report (TCR) presents an overview of single-shell tank (SST)
241-C-108 and its waste contents. It provides estimated concentrations and inventories for the waste components based on the latest sampling and analysis activities and background tank information. This TCR describes the results of three auger samples, a core sample, and headspace gas and vapor samples, all taken in 1994. Tank 241-C-108 began operation in 1947 and received waste until it was removed from service during the fmt quarter of 1976. Interim stabilization and intrusion prevention of the tank were completed in 1984 and 1982 respectively, therefore, the composition of the waste should not change until pretreatment and retrieval activities commence. The concentrations reported in this document reflect best composition estimates of the waste based on the available &ta. This report supports the requirements of the Hanford Federal Facility Agreement and Conse# Order-@cology et ~. 1994), Milestone M-44-W, and the Ferrocyanide Tank Safety Program Milestone I2B-95-123(Jordan 1994). Tank 241-C-108 is on the Ferrocyanide Watch List.

1.1 PURPOSE

The primary purpose of this TCR is to mmmarim the information concerning the use and the contents of tank 241-C-108. Where possible, this information will be used to assess issues associated with safety, operations, and process development activities. This TCR also provides a reference point for more detailed information concerning tank 241-C-108. 1.2 SCOPE The core and auger samples discussed in this report were obtained in accordance with WHC-SD-WM-TP-211, Tank 24I-C-108 T& Characterization Plan (Schreiber 1994a, 1994b). These samples were subsequently analyzed according to WHC-SD-WM-SP-004, T& Safety Screening Data Quality Objective (Safety Screening DQO) (Babad and Redus W94). Because tank 241-C-108 is on the Ferrocyanide Watch List, the acquisition and analysis of the samples are also governed by WHC-SD-WM-DQO-007, Data
Requirements for the Femocyanide &@ty Issue Developed through the Data Quafi~ Objective Process (Femocyanide afetyProgramDQO)(Meacham al. 1994). Sampling S et

andanalysisactivities are therefore focused on either the verifkation of the Watch List tank
status or identification of any unknown safety issues associated with the tank. The sampling events include a core sample taken on June 2, 1994; two auger samples collected on
WHC-SD-WM-ER-503, kW. O November 18, 1994; andanauger sample obtained on December 12, 1994. Analyses ad.essed eight primary parameters: energetic, percent water, cyanide content, metals comcnt (by inductively coupled plasma procedure), total alpha activity, total organic carbon content, gamma energy level, and total beta activity. The headspace gas and vapor samples discwed in this report were CQllectedand analyzed in accordance with WHC-SD-WM-DQO-002, Data Quafiiy Objemvesfor Generic In-Tank Health and SafeV Vhpor Issue Resolution, March 7, 1994 (Osborm and Story 1994) to help determine the potential risks to tank farm workers from potential fugitive emissions fi-omthe tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in WHC-EP-0526, Program Plan for the Resolution of Tank Vapor Issues (Osborne and Huclcaby 1994). Detailed analytical results of the vapor samples obtained from this tank are reported in WHC-SD-WM-EIM23, T& 241-C-1(?8 Vizpor San@ing and Analysis Tank Characterization Repoti (Huckaby 1995a).

,-. ,.

WHC-SD-WM-ER-503, RW. O 2.0 HISTORICAL TANK INFORMATION
This section describes tank 241-C-108 based on historical information. The first part details the current condition of the tank, followed by discussions of tank background, transfer history, and process sources that contributed to the tanks waste, including an estimate of the current contents. Events that may be related to tank safety issues, such as potentially hazardous tank contents (e.g., ferrocyanide, and organics) or off-normal operating temperatures, are included. The fd part summarhs surveillance data available for the tank. Surface-level data are used to assess tank integrity (e.g., detect leaks) and to provide clues to internal activity in the solid layers of the tank (e.g., shrinkage from drying). Temperature data are provided to evaluate the heat-generating characteristics of the waste. 2.1 TANK STATUS
As of June 30, 1995, tank 241-C-108 contained 250 kL (66 kgal) of noncomplexed waste
(Harden 1995). The volume of the various waste phases found in the tank are shown in Table 2-1. As shown in Table 2-1, the waste is comprised entirely of sludge with no pumpable liquid remaining. Further, HanIon (1995) has listed this tank on the Ferrocyanide Watch List since January 1991 and identifies it as a low heat-load tank. The tank is categorized as sound. The tank has been interim stabilized, and intrusion prevention has been completed.

Beginning in May 1955, UR was routed to the 244-CR Vault for scavenging with nickel ferrocyanide (Simpson et al. 1993). The scavenged waste was mtumed to tanks to allow the waste to settle; was then be sampled and decanted to a crib (for a futther discussion of ferrocyanide scavenging, see WHC-SD-WM-TI-648, T& Characterization Reference Guide [De Lorenzo et al. 1994]). Tank 241-C-108 was used as a primary settling tank from the
WHC-SD-WM-ER-503,RW. O Figure 2-1. Tank 241-C-108 Riser tition.

241-C-108

NORTH w

SALTWELL PUMP PIT

C4 C3 C2

LOCATION KEY PLAN

WHC-SD-WM-ER-503,Rev. O Figure 2-2. Tank 241-C-108 Cross-Section.
TEMPERATURE PROW TUEES (BLANKED)

LIOUID LEVEL INO r

BKATNER

~ILTER

SALTWELL ~TEMPfRATURE PROBE

O.SOm tl.Oftl -1

WHC-SD-WM-ER-503, R(W. O fmt quarter of 1956 through 1957, receiving scavenged waste from tanks in the C, B, and BX Tank Farms. During this time, the tank received more than 7,570 kL (2,000 kgal) of in-farm fermcyanide scavenging (TFeCN) waste; about 662 kL (175 kgal) of waste remained in the tank in early 1958 following the conclusion of the scavenging campaign (Agnew et al. 1994a). Agnew (1993) estimates that the settling of TFeCN waste added an additional sludge layer of about 57 kL (15 kgal) to tank 241-C-108. However, most of the TFeCN sludge is predicted to have been removed from the tank in a later transfer. During 1960 and 1961, the tank received supernate (most likely Plutonium-Uranium Extraction ~acility] Pcladding waste [CWP] supernate) from tank 241-C-105 and apparently CWP directly from PUREX. During the same period, supernate was transferred from tank 241-C-108 to tanks 241-BY-101 and 241-BY-105. Agnew (1993) predicts a sludge layer of about 151 kL (40 kgal) resulted fhm the CWP waste, _ tie seco~ q-r of 1964, SUINXIM* -ferred W= fkom tank 241-C-108 to in the 241-BX Tank Farm. During 1%5 and 1966, the tank received waste from the Hot Semiworks Plant (I-IS)waste and HS supernate from tank 241-C-107. From 1%5 to 1969, supernate was intermittently transferred from tank 241-C-108 to tank 241-C-102. An unsubstantive transfer during the fourth quarter of 1%9 may have lowered the waste volume in tank 241-C-108 to 522 kL (138 kgal). Agnew (1993) predicts this transfm would have removed the CWP sludge layer and much of the TFeCN sludge layer. However, the receiving tank for this transfer is not identifkd and no other documentation shows this to have occurred. During 1970 and 1973, tank 241-C-108 received supernatant wastes from tanks 241-C-110 and 241-C-104. Records indicate these supernates were likely a mixture of wastes, including PUREX organic wash waste, ion exchange waste, reduction oxidation waste, N Reactor waste, decontamination waste, and laboratory waste (Agnew et al. 1994). Supernate was pumped from the tank during 1975 and early 1976; and tank 241-C-108 was removed from service in 1976. Salt-well pumping was completed in 1978, leaving a total waste volume of about 246 kL (65 kgal) in tank 241-C-108 (Welty 1988). Intrusion prevention was completed on December 15, 1982, and the tank was designated as interim stabilized on March 9, 1984. The process history of tank 241-C-108 as mmmarkd is presented in Table 2-3 and Figure 2-3. from Brevick et al. (1994a and 1994b)

2.4 SURVEILLMVCE DATA

Tank 241-C-108 surveillance consists of surface-level measurements, temperature monitoring inside the tank, and leak detection dry well monitoring for radioactivity outside the tank. The data are relevant because they provide the basis for determining tank integrity. Surface-level measurements are used to detect major intrusions into the tank. Dry wells located around the perimeter of the tank are used to detect increased radioactivity from a possible leak to the soil.
2.4.1 SurfacAevel Readings
The surface level of the waste is monitored quarterly using a manual tape through riser 8. A surface-level mewmment of 48.3 cm (19 in.) was obtained on July 2, 1995. Surface level has &en measured as being between 33.7 cm (13.3 in.) and 50.8 cm (20 in.) from January 1991 to January 1995. The baseline surface level has been established at 49.5 cm (19.5 in.) (Barnes 1993). There is no criterion for a decrease in level, and a 5.1 cm (2-in.) maximum increase is allowed. Quarterly surface-level meammmm fiomwhenthe tank became active through 1994 are depicted in Figure 2-3.
WHC-SD-WM-ER-503. Rev. O Figure 2-4. Tank 241-C-108 Tank Layer Model.

a) z s 68

Vo!ume
2.4.2 Internal Tank Temperatures Temperature data for tank 241-C-108 are recorded by 16 thermocouples on a thermocouple tree inserted into the tank in riser 5. A second thermocouple tree was installed at riser 1 in July 1993. The fmt thermocouple in each tree is about 45 em (1.5 fi) from the bottom of the tank. Themnocouples 1 through 9 are evenly spaced 60 cm (2 ft) apart on the thermocouple tree. Thtmnoeouples 9 through 11 are spaced 1.2 m (4 ft) apart (see Tran [1993] for thermocouple elevations). Because this tank is on the Femcyanide Watch List, temperature readings from both thermocouple trees are recorded continuously by the Tank Monitoring and Control System (TMACS). On August 24, 1995, temperatures from thermocouples on the riser 1 tree ranged from 25 C (77 F) to 26 C (79 F); temperatures from thermocouples on the riser 5 tree ranged from 24 C (75 F) to 25 C (77 F). The historical data for the riser 5 tree show similar temperature readings for the fmt 11 thermocouples. Themmeouple 12 has five recorded data points spanning from 1989 to 1993. Thermocouples 13 through 16 have only two reeorded data points. The mean temperature for probes 1 through 11 for the reeorded data is 27 C (81 F), the minimum temperature is 17 C (63 F), and the maximum temperature is 33 C (91 F). Plots of the riser 5 thermocouple readings for tank 241-C-108 can be found in Supportzng Document for the Northeast Quadrant Historical T& Content Estimate for C Tank Farm (Ikevick et al. 1994b). A graphical representation of the weekly high temperature fkom the riser 5 thermocouples can be found in Figure 2-5.
WHC-SD-WM-ER-503, RW. O Table 24. Tank 241-C-108 Historical Tank Content Estimate.1 (sheet 2 of 2)

WHC-SD-WM-ER-503, R(W. O

I94-AUG-015

94-AUG-015

c (flutes 10-14)

Upper half Lower half

36.8 63.2

Riser 4

Esch, R. A., 1995, 216-Day Final Reportfor Tank 241-C-108, Auger Samples 94-AUW12, 94-AUW15 and hsh Mode, Core 61, WHC-SD-WM-DM82, Rev. 1, Westinghouse Hanford Company, Richland, Washington.

94-AUW14,

[GEA], inductively coupled plasma ~CP], total organic carbon ~OC], total inorganic carbon ~C], cyanide, and strontium). Core and auger information, sample identification, digestion method, and analyses performed are mmmarkd in Table 3-4. Figure 3-3 is a flowchart of the steps taken to analyze the waste samples from tank 241-C-108. All the analyses were performed at the 222-S Laboratory following the procedures outlined in the TCPS (Schreiber 1994a, 1994b) and as required by the relevant DQOS at that time (Meacham et al. 1994; Babad and Redus 1994). The analytical methods and procedures are listed in Appendix A. 3.2 DESCRIPTION OF VAPOR SAMPLING EVENT (1994) Headspace gas and vapor samples were collected from tank 241-C-108 on August 5, 1994, by the Westinghouse Hanford Company (WHC) Sampling Mobile Laboratory (WHC 1995). Sample collection and analysis were perfomwd as directed by the sample and analysis plan (WHC 1995). The tank headspace temperature was determined to be 25 C (77 F). Air from tank 241-C-108 headspace was withdrawn via a 7.O-m(23-ft) long heated sampling probe mounted in riser 4 and transferred via heated tubing to the vapor sampling system sampling manifold. All heated zones of the vapor sampling system were maintained at approximately 50 C (122 F).
WHC-SD-WM-ER-503,WV. O Figure 3-2. Sample Auger Breakdownand Compositing Procedure.
WHC-SD-WM-ER-503, RIW. O Table 34. Tank 241-C-108 Sample Data Wnruary.1 (shet 1 of 2)

Core 61

Fusion
Total dphil, GEA, ICP, wllsr ICP, %lr DSC, TGA, TOC, cyanide GEA, mSr GEA. mSr
s94m384 S94TOO03.99 S94TOO0401 s94m385 S94TOO0400 S94TOO0402 s94m331 S94TOO0335 S94TOO0337 S94TOO0332 s94m336 s94m338 s94m367 s94m361 S94TOO0367 S94TOO0368 S94TOO0362 S94TOO0368 S94TOO0369

s94m363

Acid Direct Fusion Acid

Lower I

D&t

I TOC, cyanide

IGEA, mSr IGEA, mSr TOC, cyanide GEA, mSr GEA, mSr TOC, cyanide IGEA, mSr
Fusion Acid Direct Fusion Acid D*t Fusion Acid Direct Fusion Direct Fusion

Lower I I A

IGEA, mSr TOC, cyanide ICP DSC, TGA Total alpha ICP

4.9.3 Total Nonmethane Organic Compounds
The OGIST measured the totaI nonmethane organic compound co~ntration in three SUMMA canister samples using the EPA TO-12 method (Rasmussen 1994a). The sample mean was 0.35 mg/m3, with a standard deviation (of the data) of 0.02 mg/m3. Although data
WHC-SD-WM-ER-503, *V. O Table 4-17. Tank 241-C-108 Tentatively Identifkd Organic Compounds in T~ple Sorbent Tube Samples.1 (sheet 1 of 3) ;.:, ;,:,:.: :+,y,:*&.j::,:,:::.:.x,. :.:.,,,,,.,,.,.,..L+.*.,.w.~. ~.,.,. :.:+:. ,,:,,::yw ,+.,.,.X.:. :.,.,,,,,:,.,.+y.:.:.;. i.:.,::,.:.: fg=-: %$$.$./.+.+,X<.*,.+,+ ~yx *X. ;., -.ky.:;,. <$:4!*.> w?g=-~.> ~~ w?-. . ,. ,.~~~f~wwfww%s~fi%R.::.. ?:.:,.,.. :., l-Butene Methane$trichlorofluoro Acetic acid Acetic acid Propanoic acid Hexanal Cyclotrisiloxane, hexamethyl Alkanone Heptanal 4H-1,2,4-Triazol-3-arnine, 4-ethyl _Ol, 2-Butoxy Cyclobutane, 1,1,2,3,3-pentamethyl Cyclotetrasiloxane, octamethyl Benzene, (l-methylethenyl)octanal l-Hexanol, 2-Ethyl l-octanol Ethanone, l-phenyl Benzenemethanol, a,adimethyl Nonanal Benzoic acid, 2-[(trimethylsilyl)oxy]-trimethylsilyl ester l-nonanol Beruenarnine, N-phenyl 1,3,5,7-Tetraazatricyclo[3.3. 1.13,71decane 2,5-Fyrrolidinedione, l-methyl Undecanal Decanoic acid Alkane Butanoic acid, butyl ester and siloxane 106-98-9 75-69-4 64-19-7 64-19-7 79-094 66-25-1 541-05-9 111-71-7 42786-06-1 111-76-2 57905-86-9 556-67-2 98-83-9 124-13-0 104-76-7 111-87-5 98-86-2 617-94-7 124-19-6 3789-85-3 143-08-8 112-31-2 122-394 100-97-o 1121-07-9 11244-7 334-48-5 -0.038 0.042 0.083 0.038 0.003 0.010 0.026 0.012 0.009 0.004 0.001 0.002 0.020 0.001 0.016 0.006 0.004 0.001 0.006 0.018 0.002 0.002 0.011 0.001 0.001 0.001 <0.001 <0.001 <0.001 <0.001 0.002
WHC-SD-WM-ER-503, Rev. O Table 4-17. Tank 241-C-108 Tentatively Identified Organic Compounds in Triple Sorbent Tube Samples.* (sheet 2 of 3) IButanoic acid, butyl ester ITetradecane Dodecanal Mixture Decane, 1,1-oxybis 5,9-Undecadien-2-one, 6, 10-dimethyl-,(Z)2,5-Cyclohexadiene-l,4dione, 2,6-bis(l, 1dimethylethyl) Allmnol and alkyl benzene C12-Allcene Alkene 2,5-Cyclohexadiene-l ,4dione, 2,6-bis(l, 1dirnethylethyl) Hexadecane Tetradecanoic acid Decanoic acid Dodecanoic acid Tetradecane Dodecane, 2-methyl-6-propyl Propanoic acid, 2-methyl-1(1,ldimethylethyl-2methyl-l ,3-propanediyl) ester Benzenamine, N-phenyl Hexadecananu de N-Hexyl-benzene-sulfonamide para-T-Butyl Benzoic acid, methyl ester 1.2-BenzenedicarboxYlicacid, bis(2-ethylhexyl) ester. Octadecanoic acid Mixture l-Hexadecanoil and others Mixture (alkane and alkanoic acid) Mixture 9-Octadecenoic acoid, (Z)I i 109-21-7 629-59-4 112-54-9 2456-28-2 3879-26-3 719-22-2 --719-22-2 544-76-3 544-63-8 334-48-5 143-07-7 629-59-4 55045-08-4 74381-40-1 122-39-4 629-54-9 -117-81-7 57-114 --112-80-1 I i <0.001 0.002 <0.001 <0.001 <0.001 0.002 <0.001 0.001 0.003 <0.001 0.002 0.001 0.002 <0.001 0.010 <0.001 0.003 0.017 0.009 0.001 0.003 0.002 0.001 0.001 0.001 0.002 0.002 0.002 0.003 I

Sum of beta emitters Total beta result
Relative wrcent difference (%) pCi/g = microcurics per gram

30.17 --

WHC-SD-WM-ER-503, RW. O The total alpha comparison is providd in Table 5-2. The lAm and W values were taken from Appendix B. The total alpha result was obtained from Table 4-3. As evident in Table 5-2, there was good correlation between the two results with an RPD of only 20.5 percent.
5.1.3.3 Mass and Charge Balance. The principle objective in performing a mass and charge balance is to determine if the measurements are self-consistent. Because of the limited number of analyzed metals and anions, all results tlrom the auger samples were used in the calculations.
With the exception of sodium, all cations listed in Table 5-3 were assumed to be present in their most common hydroxide or oxide forms, and the concentrations of the assumed species wem calculated stoichiometrically (from the data in Table 4-6). There may be some argument about whether certain species are hydroxides or oxides, but the difference in molecular weight has a minimal effect on the overall mass balance. Although smaller concentrations of other forms of the species are probably present in the waste, they are not included in order to keep the mass and charge balance calculations simple and consistent. The cyanide in the tank is assumed to be present as the precipitate N~NiFe(CN)b. The amounts of Fe and Ni in that compound were determined and deleted from the cation mass balance, since they are already being included in the anion balance through the cyauide assumed species calculation. These amounts are shown in column four of Table 5-3. Because precipitates are neutral species, all positive charge was attributed to the sodium cation. All anions listed in Table 5-4 (taken from Table 4-10) were assumed to be present as soluble or insoluble sodium salts, and were expected to balance the positive charge.
Table 5-2. Comparison of Total Alpha Activity with the Sum of the Individual Activities.

24,400

0.00936

sum of alpha emitters

Total dphil resdt Relative percent difference (%)
pCi/g = microcurics per gram

0.0416 <0.0511 20.5

Table 5-3. Cation Mass and Charge Data.

Al Ca Fe Ni u Na Totals

52,100

12,700 7,170 8,94,100

Al(OH)~ CaO NazNiFe(CN)c FeO(OH) Na2NiFe(CN)G NiO u~o* Na+

WHC-SD-WM-ER-503, Rev. O The visual descriptions of the auger samples described the obvious heterogeneity of the samples with regard to the color (off-white to brown); texture (crumbly to paste-like); and the vaIYingdegrees of hard, chun@ material embedded throughout the samples. This evidence also strongly implies some heterogeneity within the tank.
5.4 COMPARISON OF TRANSFER HISTORY AND ANALYTICAL INFORMATION
Analytical data from the 1994 auger sampling events are compared to the HTCE projections based on the tanks process history in Table 5-6. The HTCE values in column two are the same as those reported in Table 2-5. The analytical results presented in column three are taken from Section 4.0. Conversions have been made when needed so that units and chemical compounds are comparable. The comparisons revealed that the HTCE values and the analytical data agree quite poorly. Several instances deserve mention. The 137Cs omparison is closer if the core composite c sample mean of 41,300 Ci is used. For %3r, the data result was much higher than the predicted number. This may be indicative of the presence of HS waste, which the tank received between 1%5 and 1%9. The TIM (Agnew et al. 1995) does not predict that HS waste is still present in the tank, consequently, the HTCE Sr value is low. On the other hand, HTCE predictions for uranium and iron were substantially higher than their analytical results. The TIM predicts that two-thirds of the sludge in tank 241-C-108 is composed of UR waste, which is rich in both uranium and iron. It is possible that UR waste constitutes a smaller proportion of the waste, which would account for the lower analytical values.
5.5 EVALUATION OF PROGRAM REQUIREMENTS
The core and auger samples taken in 1994 were acquired to meet the requirements of the Femocyanide Safety Program DQO (Meacham et al. 1994) and the Safety Screening DQO (Babad and Redus 1994). Evaluation of data in terms of operational, environmental, or process development requirements was not required. The Tank vapor Sampling DQO W= also evaluated against the August 5, 1994 sampling event. The requirement that the vaporspace be below 25 percent of the LFL was met in this case.

Safety Evaluation

Data criteria identifkd in the Ferrocyanide Safet DQO (Meacharn et al. 1994) and the Safety Screening DQO (Babad and Redus 1994) are used to asseas b aaf~ of the waste in tank 241-C-108. For a proper saf@ assessment, both DQOSrequire samples fiomtwo widely spaced risers. The Ferrocyanide Safety Program DQO identities two primary data requirements for tanks on the Ferrocyanide Watch L~t: total fuel and moisture content. Total fhel content is measured by DSC, and the decision limit is 8 wt%, or 481 J/g. Moisture content is measured by TGA, and the safety limit is dependent on the fhel content.

WHC-SD-WM-ER-503, RW. O If the fuel content is below 8 wt%, the moisture content is not a concern for the ferrocyanide safety issue. Above 8 wt% fuel, the decision threshold for percent water is determined according to the equation: 4/3 (fuel content - 8).
Table 5-6. Comparison of Historical Tank Content Estimate and Analytical Data. 104 W (355 Btu/h) 492 W (1,680 Btu/h) 59.7 Water (wt%) 38.8 TOC (wt% C [wet]) 0.082 0.0945. *.y.~J::::;x.>y.<.:.,,.,.>:.<.;.j.:.:::::::,::::Y:.:,:.:.:,:.:: :.:jii1::::w.::::::w;:i.:.:::*:j:;$.y#.::j:f;<:i::;::y~.;$r. :.,.;~: ;;. <v~:ypk::~::*s:s*&~<*~ fl.*.:v~,<.x.,.:<=,tig )~m~W##M~ @d$$$$@gB%~$84%w,%#$@$ ,.,.,.,,.:,:.:fl:,.:,,.,.,,, ,.,.,,.,,, :::,;:; ,.,.,,,.,.,,,.,.,.,<. ,,.,.,,,.,.,,,., ,,.,,.,,.,,:.:.:., =*/iii&iMi-#ii* Na 27,400 32,900 2,560 Al 18,200 Fe 25,200 2,510 Ni 1,270 2,940 Ca 1,490 4,450 :,.,. :.:~:.:. +,:{. ,.,. ;.;:i.i.,.::,:~,:~,,.y.:y,i.>:.:.:.:., ; :.y.y.::..,,.:.::;. :.: ~ ,.,. :<.X ;.:.::<:*:, ::,x.,:,:,:,:::::,::,, :;:.<.. ;.:.:.;,:,:,:,.,.: :.:.:,:.,., >:,:.>:.:,.,.,:.:.:.:,:,:,:,:}.:, :::;::. ~:::}. ; ::::::::: :.:fi :::.:,:::.,.,,.,.,.:.:.:.:, ::::;:.,.~,.Y$P:J.:.:. YJ:.:.,,,.,:*. -.i,$>f. !$~B&@#$>&+=$> i..,>%fi$@$&s$,.,,.,.,.,.,.,..~ ,.:,&~i###$,,,~ ,w.-pvwr+w. ~ ~.,, ,. ::,..~~~..i. NO~ 25,200 15,600 NOz447 8,650 coj23,570 4,170 PO*> 10,700 28,200 F523 1,320 c254 lFe(CN)b4 1,100 941. 137CS Sr 239%
u lWet weight basis HTCE w Btulhr kg Ci = = = = = Historical Tank Content Estimate watts British thermsl unitdhour kilograms curies

Heat load

21,000 Ci 845 Ci 1.02 Ci 6,410 kg
90,700 Ci 9,450 Ci 3.28 Ci 147 kg
WHC-SD-WM-ER-503, Re!V. O All differential scamdng calorimetric analyses were endothermic with ONO exceptions: exotherrnic reactions were observed in both the primary and duplicate runs for subsamples S94TOO0292 S94TOO0291.The energy content of the largest exotherrn (on a wet weight and basis) from subsample S94TOO0292 was -33.7 J/g, while the highest for subsample S94TOO0291 was -62.5 J/g. The respective corresponding dry weight results are -50.3 J/g and -116.3 J/g, clearly satisfying the 481 J/g criterion. Because the required moisture content is dependent on the fuel content, an estimate of the fuel as ~~NiFe(CN)d based on the average dry weight cyanide value (from Table A-20) was calculated. The 3,370 pg/g of cyanide is equal to a fuel content weight percent of 0.684. Because the fbel content is <8 wt%, the moisture content is inconsequential for the ferrocyanide issue. Because cyanide is known to degrade, the N~N~e(CN)6 inventory that was estimated to have been placed in the tank, 7,950 kg (Borsheim and Simpson 1991), was compared to the inventory estimate of 2,400 kg based on the 1994 analytical data. These calculations indicate that more than two-thirds of the ferrocyanide that was originally placed in the tank has degraded. The requirements of the Safety screening DQO @abad and Redus 1994) were met in all but one respect: the moisture content in two of the subsarnples from sample 94-AUG-012 was below the 17 wt% criterion. The primary TGA result for subsample S94TOO0288 was 15.35% H20 and the duplicate was 2.995, for an average of 9.17 wt%. A renm exhibited a percent water of 6.01. Although the average weight percent water between primary and duplicate results for subsample S94TOO0290 was 18.8, the primary result was 9.94% H20. The rerun was also below 17 percent, with a result of 12.0 percent. The overall tank average was 38.8 wt% HZO. The criticality issue is assessed using the total alpha concentration; the safety screening criterion is 1 g/L. Because the laboratory reports total alpha in units of pCi/g, the 1 g/L threshold can be converted into 43.9 pCi/g using the tank density of 1.40 g/mL. All of the results were far below this limit. The fd analyte required by the Safety Screening DQO (Babad and Redus 1994) was the gas composition of the tank headspace. The established safety limit for gas concentration is 25 per&nt of each gass lower fl=bility limit. None of the gases of concern exceeded this 25 percent limit. Table 5-7 lists the analyses required by the Safety Screening DQO, the sampling points, and the analytical results. The ferrocyanide DQO identifies six secondary data requirements that, although not dmtly involved in determining safety category of the tank, will expedite fd resolution of the the Ferrocyanide Safety Issue. In addition to total cyanide (discussed previously), measurements and of the tank temperature and the nickel, TOC, 137CS, Sr concentrations are required. Decision limits were not established for these analytes. The nickel concentration is meamred because nickel is a signature analyte of the nickel ferrocyanide scavenging process (the only source of added nickel); the presence of nickel offers analytical evidence that femocyanide once existed in the tank (Meacharn et al. 1S94). The 8,410 pg/g nickel concentration shows that tank 241-C-108 did receive ferrocyanide waste.

Sdn@es 94-AUG012, 94AUG014, 94-AUGO15 and Push Mode, Core 61 (Esch 1995).
Column 8 lists the overall mean, which is obtained by averaging concentration values fkom the auger samples for the two different risers. For example, when sample means for 94-AUG-012 (riser 7), 94-AUG-014 (riser 7), and 94-AUG-015 (riser 4) are available, the means of the fnt two samples (both fkom riser 7) are averaged, and this result is then averaged with the mean tim the second riser (riser 4) such that each riser is weighted equally. Results from analysis of the cwe sample were not used in any of the overall mean calculations. They are presented in Appendix B for informational purposes only.
The lastcolumn lists an error estimate, relative standmd deviation (RSD) of the mean. This
is defined as the standmd deviation divided by the mean, multiplied by 100. Relative standard deviations were calculated only for those analytes in which all values were detected, and only on the preferred data sets used to derive the reported analytical mean for a given analyte. Numbers preceded by a less than symbol (<) indicate that the analyte was noted, but was below the analytical instruments calibrated detection limit for the sample. The values listed are the detection limit; they are used in all calculations except error estimates.

B.3 REFERENCES

Esch, R. A., 1995,216-Day Final Repon for T& 241-C-108, Auger San@s 94AUGO12,
94-AUG014, 94AUG015 and Push Mode, Core 61, WHC-SD-WM-DP-082, Rev. 1, Westinghouse Hanford Company, Richland, Washington.
Table B-1. Tank 241-C-108 Amlvtical Data: ALUMINUM.1.
t%sh Mode, tire 61, WHC%D-WM-DP-082, Rev. 1, Westingho& Hanford Company, Richland, Washington.

ICP f RSD

= = = =
Microgram per gram Inductivelycoupled plasma Fusion digcation Relative standard deviation of the mean
Table B-2. Tank 241-C-108 Analytical Data: CALCIUM.1.
94-AU(74)12, 94-AUGO14, 94-AUGO15 and l%sh Mtie, Cbre 62, WHC-SD-WM-DP-082, Rev. 1, WeatinghouaeHanfoxtlCompany, Richland, Washington. VW, R.& ~~, 21~~ EM R~n

for r~

zJ1-c.lm, @er _&.$
Microv per gInductivelycoupled plasti. Fusion digestion Relative standard deviation of the mean
Mode, Core 62, WHC-SD-WM-DP-082,Rev. 1, WcstinghouacHanford Compauy, Richland, Washington.
Microgram pergram Inductivelyoupled c plasma Fusion digcation Relative standard deviation themean of

I Each R. A.,

GEA f a
= Microcurie per gram = Gamma energy analysis = Fusion digestion = Acid digestion
of = Relative standard deviation the mean
Table B-10. Tank 241-C-108 Analytical Data: COBALT-60.1
s94TOOo400I GEA.a.Yo I S94TOO0337 I

s94m399

s94m338

I S94TWM01 I

1995, 216-Day Ffnal Reportfor Tank 241-C-108, Auger Samples 94-AUG012, 94AUW14, 94-AUG015 and I%sh Hanford Company, Ricidand, Washington. Mode, Core 61, WHC-SD-WM-DP4182, Rev. 1, Westinghouse

EscII, A., 1?.

I <0.00298 I cO.00282 I <0.002901 I I <0.00372 I <0.00350 94-AUG-015 I Lawer % I <0.00328 - S94TOO0402 I S94TOO0340 I 94-AUG-012/014I Composite I <0.<0.00718 I <0.00703 I <0.00498 S94TOO0404 94-AUG-015 I Composite I

1 I I m m L m I n 1 I

94-AUG-014 I Lower % 94-AUG-015 I upper % 94-AUG-015 I Lower % 94-AUG-012.I Upper % 94-AUG-014 I Lower % 94-AUG-015 I Umer %

m 1. 1

I <0.0100 I <0.0163
I <0.00943 I <0.00972 <0.0137 I I <0.0180 I <0.0172 I

n 1 I I

<0.0223
<0.0174 I <0.0199 II I
<0.00284 I <0.00418 I <0,00351 I
[ <0.00714 ! <0.00650

I <0.00585

<0.00410 I

pCi/g GEA f a

Microcurieper gram Gamma energy analysis Fusion digestion Acid digestion
Table B-II. Tank 241-C-108 Analytical Data: EUROPIUM-154.i

..,:.,.,..,,.

3EA.f.lWEU
s94m335 94-AUG-012 <0.0294 Upper % <0.0295 <0.0295 <0.0533 94-AUG-014 <0.0437 s94m336 <0.0485 Lower % <0.0461 94-AUG-015 <0.0826 s94m399 Upper ?4 <0.0783 <0.0805 <0.0685 94-AUG-015 s94TOOo400 Lower % <0.0573 <0.0460 3EA.a.l~Eu <0.0135 S94TOCK)337 94-AUG-012 Upper % <0.0132 <0.0134 <0.0141 <0.0185 S941W10338 94-AUG-014 Lower % <0.0224 <0.0205 94-AUG-015 Upper % <0.0123 S94TOO0401 <0.0115 <0.0119 <0.0124 94-AUG-015 <0000903 S94TOO0402 Lower % <0.0107 S94TOO0340 94-AUG-012/014 Composite <0.0465 <0.0455 <0.0460 <0.0279 <0.0102 S94IWM404 94-AUG-015 Composite <0.00948 <0.00984 Wch, It. A., 1995,216-Day nal Rqxni for T& 241-C-MM, Auger Samples94-AUW12, 94-AUG-014, !M-AUG-015and Push R Hanford Company, Richhmd, Washington. Mode, Core 61, WHC-SD-WM-DP-082, Rev.1,Westinghouse

/lci/g

Hi I&v

= Microcwic per gram

:.,.:.,.:.:.:.,.:.:.:.:.,.:.:l.*,.:,:..\..
T& 241-C-108, Auger Samples 94-AUG012, 94-AUG014, 94-AUGO15 and Ftuh Hanford Company, Richland, Waahiigton. Mode, Ore 61, WHC-SD-WM-DP-082, Rev. 1, Wcatinghouac

= Highlevel

= Fusion digestion = Aciddigcation
= Relative atandad deviation of the mean
Table B-16. Tank 241-C-108 Analytical Data: TOTAL ALPHA.1

MW.d.Total Mpha

S94TOO0289 S94TOO02%

S94TO(K)298

<0.1 TOP%: A2 I <0.0588 I 0.108 I <0.0834 I 94-AUG-014

I 0w25F I Y: I W81

S94T(MK)297

s94m367 S94m368

IThird !4: c I <0.0317 ,I <0.0317 I <o.031794-AUG-015 IToP!4: AI <0.0341 I <0.<0.0341 second <0.0290 <0.0361 <0.0326 %: B I I I

S94ti369 s94m370

APC.f.Total Alpha

Third !4:CI

<0.0363 I

I <0.0362

I <0.0363

I Bottom

<0.167 I <0.02641<0.0967

core 61

<1.38 I I

<0.925 I I

<1.15
Ed , R. A., 1995, 216-DoyFinal Reporlfor Td 241-C-I(?8, Auger Samples 94-AUW12. 94-AUG014. 94A UW15 ond Fksh Mode, (he 61, WHC%D-WM-DP4182, Rev.1,Wcatingho~Hanford Company, I&land, Waahi&ton. pCi/g APC = Microcurie per gram = Alpha proportional counting

= Micmcurie per gram

= Acid digestion = Relative standard deviation of the mean
Table B-18. Tank 241-C-108 Analytical Data: CHLORIDE.1.
%ch, R. A., 1995, 21Wkzy Final Repon for Tank 241-C-108, Auger Sanples 94-AUW12, 94-AUW14, 94-AUG015 and tih Rev.1,Wcatinghouac Hanford Company, Richland, Washington. Mode, Cbre 62, WHC-SD-WM-DP%82,

= Microgramper gram

= Ion chromatography = Water digcation
,.:.:.:.:.:.:.:.:.:.:.:.:. :.:.:.:,:,:,:,:.t:::.::t::::<.:w..~y.:.:.:.:.:.:.,.:. :,:,:.fi.:~../.:.:.:.:::.:::, :::::.,.:,..:.:.:..:,,.:,. Microdist/ Spec.CN-
Table B-19. Tank 241-C-108 Analytical Data: CYANIDE.i
s94m331 94-AUG-012 Upper % 781 4,990 1,980 51.6 s94m332 94-AUG-014 Lower % 5,100 5,050 S94TOO0384 94-AUG-015 Upper % 1,010 1,050 1,030 s94m385 Lower % 1,030 1,120 1,080 %sci, R. A., 199S, 16-Day inalRcpon for Tank 241-C-108, Auger Siunples!WAUW12, 94-AUW14, 94-AUW15 and Push 2 F