L o r o l C16 ( C e t y l A1 coho1 , I N C I ) - H e n k e l Locron P (Aluminum C h l o r o h y d r a t e , INC1)-Hoechst F o r m u l a t i o n F44-12-4 Clear Pumpable Antiperspirant Inqredients: A l c o h o l , SDA F o r m u l a No. 40 Arlamo1.E pop s t e a r y l e t h e r Aluminum C h l o r h y d r a t e ( % s o l u t i o n ) Water, d e i o n i z e d

Wto/, 40 5

Preparation: D i s s o l v e A r l a m o l E p o l y o x y p r o p y l e n e 15 s t e a r y l e t h e r i n a l c o h o l a t room t e m p e r a t u r e , and s t i r u n t i l c l e a r. S l o w l y add a l u m i n u m c h l o r h y d r a t e and w a t e r , s t i r r i n g u n t i l c l e a r. Package. F o r m u l a t i o n AE-12
SOURCE: I C 1 S u r f a c t a n t s : S u g g e s t e d F o r m u l a t i o n s
Roll-On Antiperspirant Raw Materials: A) Miglyol 812 (Caprylic/Capric Triglyceride) Imwitor 780K (Isostearyl Diglyceryl Succinate) Softisan Gel (Bis-Diglyceryl Polyacyladipate-1 (and) Propylene Glycol Dicaprylate/Dicaprate (and) Stearalkonium Hectorite (and) Propylene Carbonate) B) Carbopol 980 Gel 1% Abil WE 09 (Polyglyceryl-4 Isostearate (and) Cetyl Dimethicone Copolyol (and) Hexyl Laurate) Locron L (Aluminum Chlorohydrate) Preservative up to Water, C) Deosafe Perfume N / I Preparation: (A) is heated up to 50 degrees C and mixed. (B) is mixed and heated up to the same temperature. (B) is emulsified into ( A ). At 40 degrees C, (C) is added. Formulation 1.5X Deo Antiperspirant Spray with Aerosol Raw Materials: A ) Miglyol 812 (Caprylic/Capric Triglyceride) Hydagen DE0 (Triethyl Citrate (and) EHT) Locron P (Aluminum Chlorohydrate) Aerosil 200 (Silica) Perfume B) Drivosol 35* (Propane, Isopropane, Butane) *Filling: Lotion: 8% Drivosol: 92%, 3.5 bar Preparation: (A) is mixed together thoroughly. Formulation 1.5W SOURCE: Creanova Inc.: Suggested Formulations

8.50 5.00 2.00 12.50

0.50 1.00

100.00

2.00 2.00

3.00 0.10 q.s.

Roll-on Antiperspirant Lotion

Concept S t a t a m e n t : A l i g h t baby l o t i o n c o m b i n i n g t h e e r n o l l i e n c e o f R i t a l a n , R i t a c h o l and R i t a w a x , w i t h R i t a v e n a - 5 , t o g i v e a s o f t s k i n f e e l I n g r e d i e-nt-s; 1. R i t a GMS ( G l y c e r y l S t e a r a t e ) 2. Mineral O i l 3. S t e a r i c A c i d 4. Ritalan (Lanolin O i l ) 5. R i t a c h o l ( M i n e r a l O i l and L a n o l i n A l c o h o l ) 6. R i t a w a x ALA ( C e t y l A c e t a t e a n d A c e t y l a t e d L a n o l i n A1 coho1 ) 7. Propylparaben 8. D i s t i e d / D e i o n ? z e d Water 9. R i t a v e n a - 5 ( H y d r o l y z e d Oat F l o u r ) 10.Propylene Glycol 1 l. T E A (50%) 12.Methylparaben 13.Germall I I 14.Fragrance
Wt% 1.oo 9.00 2.00 3.00 1.oo 1.oo 0.10 74.70 2.00 4.00 1.60 0.20 0.20 0.20
Compounding P r o c e d u r e : Combine i n g r e d i e n t s 1 - 7 and h e a t t o 70C. H e a t 30% o f t h e w a t e r p o r t i o n t o 9 O C a n d m i x w i t h i n g r e d i e n t 9 i n b l e n d e r. Combine r e m a i n i n g 70% o f t h e w a t e r w i t h i n g r e d i e n t s - a n d h e a t t o C. Add R i t a v e n a - 5 m i x t u r e a n d m i x u n t i l u n i f o r m. Add o i l phase and m i x u n t i l c o o l. Add i n g r e d i e n t 1 4. F o r m u l a t i o n R e f. No. 123-9 Diaper Rash Ointment Concept S t a t e m e n t : A s o o t h i n g ointment t o reduce t h e i r r i t a t i o n o f rashes, c o m b i n i n g t h e e m o l l i e n t p r o p e r t i e s o f L a n o l i n , R i t a I P P and R i t a SSO. Ingredientsl 1. Petrolatum 2. L a n o l i n USP, X - t r a Oeo 3. R i t a IPP (Isopropyl Palmitate) 4. R i t a SSO ( S u n f l o w e r Seed O i l ) 5. Zinc Oxide

w>yc

39.20 14.30 14.30 3.60 28.60
Compounding P r o c e d u r e : Combine i t e m s 1 - 4 a n d h e a t t o 65C. S l o w l y a d d i t e m 5 w h i l e m i x i n g. I f n e c e s s a r y , u s e h i g h shear m i x i n g and m i x u n t i l uniform. F o r m u l a t i o n R e f. No. 123-12 SOURCE: R , I. T. A. C o r p. : Suggested F o r m u l a t i o n s

Baby Shampoo

A liquid shampoo which has a low order of eye irritation can be made by carefully selecting the detergents. In the following baby shampoo, the combination of anionic and amphoteric surfactants with G-4280 produces a formula which should be mild, effective and esthetically appealing. Inqredients: A G-4280 Sodium trideceth sulfate Lauroamphodiacetate Cocamidopropyl hydroxysultaine Sodium laureth-13 carboxylate Water Preservative

30.0 20.0 4.0 3.0 22.5 1.o 13.0

5.0 1.5

D e i o n i zed Water s i - C r y S t y r e n e - A c r y l i c Copolymer
Procedure: Add i n t h e o r d e r l i s t e d. M i x P a r t B w e l l b e f o r e a d d i n g t o P a r t A. A d j u s t t h e pH t o 6. 0 - 6. 5 and add d e s i r e d p r e s e r v a t i v e s , fragrances, e t c. Physical Properties: A p p e a r a n c e : Opaque i v o r y w h i t e l i q u i d V i s c o s i t y a t 25C: 720 c p s F o r m u l a t i o n F-696
SOURCE: Mona I n d u s t r i e s , I n c. : S u g g e s t e d F o r m u l a t i o n s
Clear Shower Gel Raw M a t e r i a l s : Texapon NSO/Sodium L a u r e t h S u l f a t e P l a n t a c a r e K / L a u r y l G l u c o s i d e ( a n d ) Cocamidopropyl Betaine L a m e s o f t PO / C o c o - G l u c o s i d e ( a n d ) G l y c e r y l O l e a t e G l u a d i n W / H y d r o l y z e d Wheat G l u t e n H y d r o l y z e d Wheat Protein NaCl Aqua, p r e s e r v a t i v e pH v a l u e : 5. 5 V i s c o s i t y mPas: 4160 WAS ( % ) : 1 6. 9 Preparation i n t h e Laboratory: M i x a l l i n g r e d i e n t s a t room t e m p e r a t u r e. A d j u s t t h e pH v a l u e , then a d j u s t t h e v i s c o s i t y w i t h s a l t. F o r m u l a t i o n N o. : 94/193/227 36.0

11.0 5.0

2.25 45.75

Shower Bath

Raw M a t e r i a Texapon NSO/Sodium L a u r e t h S u l f a t e Dehyton K/Cocamidopropyl B e t a i n e P l a n t a c a r e 1200 U P / L a u r y l G l u c o s i d e L a m e s o f t PW 45 M e t h o c e l E4M Premium E P / H y d r o x y p r o p y l M e t h y l c e l l u l o s e NaCl Water Preservatives V i s c o s i t y mPas: 6000 pH v a l u e : 5. 5 40.0 3.5

10.0 0.5 38.0 n.B.

Preparation i n the Laboratory: O f M e t h o c e l E4M Premium EP and W a t e r has t o be m a n u f a c t u r e d a c l e a r s w e l l i n g. Texapon NSO, D e h y t o n K , P l a n t a c a r e 1200 and L a m e s o f t P 45 w i l l b e s t i r r e d homogeneous one a f t e r t h e o t h e r. W W i t h c i t r i c a c i d t h e pH v a l u e w i l l b e f o c u s e d a t 5. 5. The v i s c o s i t y t u n i n g t a k e s p l a c e w i t h NaCl. F o r m u l a t i o n No. / 6 / 7
SOURCE: H e n k e l KGaA: S u g g e s t e d F o r m u l a t i o n s
Cream Body Shampoo T h i s p e a r l e s c e n t w h i t e cream c o n t a i n s J o r d a p o n C I - F l a k e and A v a n e l 5-150 CGN f o r m i l d n e s s and s o f t s k i n , w h i l e p r o v i d i n g v o l umi nous s i 1 k y 1 a t h e r. Dei o n i z e d Water 58.9 0.1 H y d r o x y p r o p y l Methylcellulose/Methocel 40-100 B N a 4 EDTA 0.2 T r i e t h a n o l a m i n e , 50% 0.1 C Sodium C12-15 P a r e t h - S u l f o n a t e / A v a n e l 2.3 S-150 CGN Sodium C o c o y l I s e t h i o n a t e ( a n d ) S t e a r i c A c i d / Jordapon CI-75 27.0 Ammonium L a u r e t h S u l f a t e / A l f o n i c 1412-A 7.0 0.5 G l y c o l S t e a r a t e / M a p e g EGMS 0.2 M e t h y l Paraben 2.5 Sodium S u l f a t e D I m i d a z o l i d i n y l Urea/Germa 0.2 2.0 Dei o n i zed Water E Fragrance 0.5 Q.S. C i t r i c A c i d , 50% pH: 6.3-6.8 V i s c o s i t y : , 0 c p s ( B r o o k f i e d # 3 @ 1. 5 rpm) Appearance: V i scous p e a r l e s c e n t l o t i o n Procedure: Disperse t h e hydroxypropyl methylcellulose i n t h e p a r t A w a t e r a t a m b i e n t t e m p e r a t u r e. W i t h good p r o p e l l o r m i x i n g , add t h e p a r t B i n g r e d i e n t s and a g i t a t e f o r a t l e a s t 20 m i n u t e s t o e n s u r e c o m p l e t e h y d r a t i o n. Add t h e p a r t. C i n g r e d i e n t s and h e a t t o 65C. When u n i f o r m , c o o l t o 40C and add p a r t D ( p r e m i x e d ). Add t h e f r a g r a n c e and a d j u s t t h e pH. The p r o d u c t i s i n i t i a l l y a nonviscous l i q u i d which develops i n t o a s o f t paste a f t e r s t a n d i n g a t room t e m p e r a t u r e. F o r m u l a t i o n F-108 Part : A

3.0 4.0 3.0 4.0 2.0 2.0 2.0 1.5 0.5 2.5
50.1 0.2 3.0 10.0 5.0 5.0 0.2 1.o 1.o
Procedure: Heat Phase A t o 75 t o 80C. H e a t and m i x Phase B t o 75C. E m u l s i f y b y a d d i n g Phase A t o Phase B. Add t h e p r e s e r v a t i v e and m i x w h i l e c o o l i n g. Pour i n t o c o n t a i n e r s a t 40C. A d a p t a t i o n o f F o r m u l a and i t s I n f l u e n c e on t h e P r o d u c t : T h e r e i s room f o r c h a n g i n g t h i s p r o d u c t b y t h e u s e o f o t h e r a c t i v e s w h i c h p r o d u c e s i m i l a r c l a i m s. The u s e o f o t h e r p l a n t o i l s w i l l n o t d r a m a t i c a l l y a l t e r t h e f i n i s h e d p r o d u c t. Worth m e n t i o n i n g i s t h e a b i l i t y o f Orange Wax t o mask t h e aroma o f t h e eucalyptus o i l producing a p r o d u c t o f low f r a g r a n c e.
Antiwrinkle Night Cream Concept Statement: A non-greasy night cream containing Pationic SBL to moisturize and smooth skin, and Tensine and Reductine to reinforce skin firmness. Insredients: 1. Distilled/Deionized Water 2. Propylene'Glycol 3. Mineral Oil 4. Lanolin X-Tra Deo 5. Petrolatum 6. Butylated Hydroxyanisole 7. Pationic SBL (Sodium Behenoyl Lactylate) 8. Ritacetyl Alcohol 50/50 (Cetearyl Alcohol) 9. Rita SA (Stearyl Alcohol) 1 0. Phenonip 11.Fragrance 12.Tensine (Wheat Protein) 13.Reductine (Oat Protein) 58.00 5.00 12.00 2.00 5.00 0.10 2.00 3.50 1.50 0.50

q.s. 5.00 5.00

Compounding Procedure: Mix items 1 and 2 and heat to 80C. Combine items 3 to 9 and heat to 80C. Add oil phase to water phase and homogenize. Cool to 35C and add items 10 to 13. Formulation Ref. No. 122-81B Cleansing Cream Concept Statement: A cleansing cream with Pationic SCL to provide skin moisture and smoothness, and a pleasant feel. Inqredients: 1. Pationic SCL (Sodium Cocoyl Lactylate) 2. Rita Cetearyl Alcohol 50/50 (Cetearyl Alcohol) 3. Rita GMS (Glyceryl Stearate) 4. Mineral Oil 5. Ritachol (Mineral Oil and Lanolin Alcohol) 6. Distilled/Deionized Water 7. Glycerine 8. DMDM Hydantoin

0.50 1.60

4.00 67.40 5.00
Compounding Procedure: Combine items 1-5 and heat to 80C. Combine items 6 and 7 and heat to 80C. Add oil phase to water phase. Cool to 35C and add item 8. Formulation Ref. No. 120-205A SOURCE: R.I.T.A. Corp.: Suggested Formulations

Cold Cream (O/W)

I a r e d i gn1-C: Polysynlane M i n e r a l Oil P a r a f f i n Wax I.P.M. Beeswax Lanolin Propylene G l y c o l P o t a s s i um H y d r o x i de A r l a c e l 40 P. O. E. S o r b i t o l Beeswax Stearic Acid Perfume & P r e s e r v a t i v e s Water

V a n d e r b i l t Co.,

I n c. : F o r m u l a No, 469
Ultra-Moisturizing Skin Cream Formula P r o f i l e : The s y n e r g i s t i c m i x t u r e o f Veegum U l t r a and C a r b o p o l w i l l c r e a t e a t h i c k , r i c h cream t h a t w i l l h a v e t h e g r e a t Carbomer f e e l w i t h o u t t h e t a c k. Veegum U l t r a w i l l i m p r o v e s t a b i l i t y and m a i n t a i n t h e v i s c o s i t y o f t h e p r o d u c t. The e m o l l i e n t s i n t h e o i l phase and t h e h u m e c t a n t s i n t h e w a t e r phase w i l l s u p p o r t l a s t i n g r e s i d u a l s k i n f e e l and m o i s t u r i z a t i o n. Inqredients: A : Water 81.44 Veegum U l t r a (Magnesium Aluminum S i l i c a t e ) 0.25 Carbomer ( C a r b o p o l 4 ) 0.25 B: G l y c e r i n 3.0 Butylene Glycol 2.0 C: Cetyl Alcohol 1. o G l y c e r y l M o n o s t e a r a t e SE ( D e r m a c a r e MS SE) 3.0 5.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e (Neobee M-5) C12-15 O c t a n o a t e ( F i n e s t e r EH-25) 1.o D i m e t h i c o n e (DC-200 f l u i d - 0 c t s ) 1.2 S t e a r e t h - 2 ( B r i j 72) 0.83 S t e a r e t h - ( B r i j 721) 0.83 D: Preservative qs E: F r a g r a n c e qs F: Triethanolamine 0.2 qs C i t r i c Acid A d j u s t pH t o 5. 6 t - 0. 3 Procedure: S t e p 1 : D r y b l e n d Veegum U l t r a and C a r b o p o l i n P a r t A. ( D r y b l e n d i n g reduces t h e clumping o f C a r b o p o l and a l l o w s f o r t h e s i m u l t a n e o u s i n t r o d u c t i o n o f i n g r e d i e n t s ). S i f t t h e powder i n t o an e s t a b l i s h e d v o r t e x i n t h e w a t e r. Veegum U l t r a w i l l be h y d r a t e d w i t h i n 15 m i n u t e s. A l l o w a b o u t 45 m i n u t e s f o r t h e Carbopol s l u r r y t o h y d r a t e completely The a d d i t i o n o f any o t h e r i n g r e d i e n t s d u r i n g t h e h y d r a t i o n p r o c e s s w i l l i n t e r f e r e w i t h t h e h y d r a t i o n o f Veegum U l t r a and w i l l r e d u c e o r even e l i m i n a t e t h e d e s i r e d p r o p e r t i e s g e n e r a t e d b y t h e Magnesium Aluminum S i l i c a t e. S t e p 2 : B e g i n h e a t i n g w a t e r phase i n S t e p 1 t o 70-75C. S t e p 3 : Once t h e h y d r a t i o n p r o c e s s i s c o m p l e t e d , add r e m a i n i n g w a t e r phase i n g r e d i e n t s f r o m P a r t B t o S t e p 2. S t e p 4 : B l e n d o i l phase i n g r e d i e n t s i n P a r t C and h e a t t h e o i l phase t o 70-75C. S t e p 5 : When b o t h p h a s e s a r e a t 70-75C, add o i l phase i n S t e p 4 t o w a t e r phase S t e p 2. S t e p 6 : C o o l t o 45C. Add P a r t D - P r e s e r v a t i v e t o S t e p 2. S t e p 7 : Add P a r t E - F r a g r a n c e t o S t e p 2. SteD 8 : Cool t o 35C. A d j u s t DH w i t h P a r t F. Product S p e c i f i c a t i o n s : V i s c o s i t y : B r o o k f i e l d LVT D V I I , Sp n d l e #TF b 0. 3 RPM: 300,OOOtc p s a f t e r 24 h o u r s. pH: 5. 3 - 5. 9 T h i s f o r m u l a p r o d u c e s a s t a b l e emu s i o n and p a s s e s 3 month s t a b i l i t y t e s t i n g a t RT, 5C, 38C, 50C and 3 c y c l e F / T.

Procedure: 1. Combine t h e i n g r e d i e n t s o f Phase A t o g e t h e r. D e t e r m i n e t h e r e f r a c t i ve i n d e x. 2. D i s s o l v e t h e p r e s e r v a t i v e s and Sodium C h l o r i d e i n t o t h e w a t e r o f Phase B. 3. Add t h e r e m a i n i n g i n g r e d i e n t s t o Phase B. D e t e r m i n e t h e refractive index. 4. M a t c h t h e r e f r a c t i v e i n d e x o f Phase B t o Phase A u s i n g w a t e r o r p r o p y l e n e g l y c o l , d e p e n d i n g o n t h e d i r e c t i o n needed. 5. Add Phase B s l o w l y t o Phase A w h i l e h o m o g e n i z i n g. ( A v o i d a i r entrapment).
SOURCE: G o l d s c h m i d t C h e m i c a l C o r p. : S u g g e s t e d F o r m u l a t i o n

Antidandruff Hair Tonic

L_n_SLred.~.ent l ?.
A : O c t o p i r o x ( P i r o c t o n e Olamine) B: E t h y l a l c o h o l
Fragrance Emulsogen E L (PEG-36 C a s t o r O i l ) D : Water Genami n K S L (PEG-5 S t e a r y l Ammoni um L a c t a t e ) D-Panthenol E: C i t r i c a c i d - - - - - > p H 5.0-6.0 Procedure: 1. Dissolve A i n B. 3. S t i r m i x t u r e D i n t o 2.
Wt% 0.10 35.00 0.30 0.60 63.20 0.30 0.50 9.s.
2. S t i r 1 i n t o mixture C. 4. F i n a l l y a d j u s t t h e pH w i t h E.
SOURCE: H o e c h s t A k t i e n g e s e l l s c h a f t : F o r m u l a B III/3006
Clear Conditioning Hair Gel

_ n s e d ie.n.t s~ I_ r

Phase A : D i m e t h i c o n e C o p o l y o l ( a n d ) C y c l o m e t h i c o n e ( A b i l EM ) 2.00 14.00 Cyclomethicone ( A b i l B 8839) 2.20 P h e n y l T r i m e t h i c o n e ( A b i 1 AV-20) 0.80 P u a t e r n i u m - ( A b i 1 Quat ) Cyclomethicone (and) Dimethiconol (and) Dimethicone 5.00 ( A b i l OSW ) Fragrance Q.S. Phase B : Water 28.20 Q.S. Preservatives P r o p y l e n e G1 y c o l 40.00 Hexylene Glycol 4.00 Glycerin 3.00 0.80 Sodium C h l o r i d e Procedure: 1. Combine t h e i n g r e d i e n t s o f Phase A t o g e t h e r. D e t e r m i n e t h e r e f r a c t i v e index. 2. D i s s o l v e t h e p r e s e r v a t i v e s and Sodium C h l o r i d e i n t o t h e w a t e r o f Phase B. 3. Add t h e r e m a i n i n g i n g r e d i e n t s t o Phase 8. D e t e r m i n e t h e r e f r a c t i v e index. 4. M a t c h t h e r e f r a c t i v e i n d e x o f Phase B t o Phase A u s i n g w a t e r o r p r o p y l e n e g l y c o l , d e p e n d i n g on t h e d i r e c t i o n needed. 5. Add Phase B s l o w l y t o Phase A w h i l e h o m o g e n i z i n g. ( A v o i d a i r entrapment). SOURCE: G o l d s c h m i d t C h e m i c a l C o r p. : S u g g e s t e d F o r m u l a t i o n s

B: Water Preservative

6.00 1.50

3.80 2.00 86.40

C: Fragrance Dyestuff solution
D: Citric acid-----> pH 4.0
Procedure: 1. Melt A at ca. 75C. 2. Heat B to ca. 75C. 3. Stir 2 into 1. 4. Stir until cool. 5. At ca. 35C add the components of C to 4. 6. Finally adjust the pH with D. SOURCE: Hoechst Aktiengesellschaft: Formula B II/1049
Creme Rinse Icgredi ents : Water Hydroxyethyl C e l l u l o s e Glycol D i stearate Cetyl Alcohol Monaquat TG Phosphol 1 p i d EFA M o n a s i l PDM Oleic Acid 86.80 0.70 2.00 2.50 6.70 0.30 0.96 0.04
Procedure: Charge w a t e r , c a r e f u l l y add N a t r o s o l 0 HHR w i t h good a g i t a t i o n. H e a t t o 50-60C and add r e m a i n i n g i n g r e d i e n t s and c o n t i n u e h e a t i n g t o 70C. Cool t o 45C and a d j u s t pH t o 4. 5 - 5. 0 w i t h 50% c i t r i c a c i d. Add c o l o r , f r a g r a n c e a n d p r e s e r v a t i v e s as r e q u i r e d. C o n t i n u e a g i t a t i o n and c o o l i n g u n t i l p e a r l d e v e l o p s. Formulation Properties: P H ys ical Appearance: White p e a r l e d l o t i o n F o r m u l a t i o n F-703 Clear Gel Hair Conditioning Rinse I n s r e d 1 en t s : Water Monafax MAP-230 M o n a t e r i c LMAB Monaquat I S I E S

w t 56

87.90 4.10 7.15 0.85
Procedure: B l e n d i n o r d e r l i s t e d a t room t e m p e r a t u r e , a d j u s t t o pH 7 , add f r a g r a n c e , c o l o r , p r e s e r v a t i v e , a n d p a c k a g e. Appearance: C l e a r v i s c o u s l i q u i d F o r m u l a t i o n F-680 Hair Conditioner

Innr%ddl.e_n_f

0.5% H y d r o x y e t h y l c e l l u l o s e i n water Cetyl Alcohol M o n a s i l PLN

Wt% 93.0 3.0 4.0

V i s c o s i t y : 2000 cps Opaque V i s c o u s L i q u i d Procedure: H y d r a t e HEC i n w a t e r , t h e n add r e m a i n i n g i n g r e d i e n t s i n o r d e r w i t h s u f f i c i e n t h e a t t o m e l t c e t y l a l c o h o l. Add f r a g r a n c e , p r e s e r v a t i v e , and t h e n p a c k a g e. Formul a t i on F-684
Creme Rinse Insredi e n t s water Hydroxyethyl Cellulose G1 ycol D i stearate Cetyl Alcohol Monaquat SL-5 Phosphol 1 pi d EFA Monasil PDM Oleic Acid Wt%

0.70 2.00

2.50 6.70 0.30
Procedure: Charge water, carefully add Natrosol 250 HHR with good agitation. Heat to 50-60C and add remaining ingredients and continue heating to 70C. Cool to 45C and adjust pH to 4.5-5.0 with 50% citric acid. Add color. fraarance and preservative as required. Continue ag tation and.cooling unt 1 pearl develops. Physical Appearance: White pear ed lotion Formulat on F - 8 Hair Relaxer
Ingredients Part A: Phosohol i old S V Propylene'Glycol 45% KOH Water

3.0 3.0 5.0

Part B : Cetyl Alcohol Monafax MAP 160 Petrolatum Mineral Oil Monasil PCA

B: Stearyl alcohol Carbopol 941 ( 0. 5 w t % s o l u t i o n ) Water Preservatives

Prodew 0 o r 0 Ethanol

M i x ( A ) i n g r e d i e n t s and add (6) t o ( A ). H e a t up t o 70-80C w i t h s t i r r i n g. C o o l down t h e m i x t u r e t o 50C a n d add ( C ) , t h e n c o o l down t o room t e m p e r a t u r e. NOTE: N o n - c a t i o n i c a n t i s t a t i c f o r m u l a t i o n. Smooth combing o b t a i n e d due t o t h e l u b r i c i t y o f Amihope L L. Forrnul a BR-02
Hair Lotion Raw M a t e r i a l s : G l y c e r e t h - PCA I s o s t e a r a t e ( P y r o t e r G P I - ) PEG-40 H y d r o g e n a t e d c a s t o r o i l PCA I s o s t e a r a t e ( P y r o t e r CPI-40) O c t y l dodecanol

1.2 3.5 0.1 1.5 5.0

B: Prodew 400
1 ,3-Butylene g l y c o l Methyl paraben Water
C: E t h a n o l Carboxymethyl c e l l u l o s e Perfume

balance 10.6 0.6

Procedure: M i x a l l i n g r e d i e n t s ( A ) and ( B ) a t 60-70C w i t h s t i r r i n g r e s p e c t i v e l y. Add ( B ) t o ( A ) w i t h s t i r r i n g. Add C a r b o x y m e t h y l c e l l u l o s e and c o o l t o 40C. Add e t h a n o l and p e r f u m e and c o o l w i t h s t i r r i n g t o 30C. F o r m u l a HLP-141

Hair Conditioner Lotion

T h i s l o t i o n i s t y p i c a l o f a modern r i n s e - o f f f o r m u l a b u t has e x c e l l e n t freeze-thaw s t a b i l i t y. Ingredients: A B r i j 721 Cetyl alcohol Stearyl alcohol S t e a r a l konium c h l o r i d e

0.9 0.6 0.5

8 Water, d e i o n i z e d
P r e p a r a t ion : Heat ( A ) t o 70C and ( B ) t o 72C. Add ( 8 ) t o ( A ) w i t h m o d e r a t e a g i t a t i o n. Cool w h i l e a g i t a t i n g t o 40C. R e p l a c e w a t e r l o s t b y e v a p o r a t i o n and p a c k a g e. F o r m u l a HC-10

Hair Conditioner Gel

Demonstrates t h e use o f F o r e s t a l l i n a s u r f a c t a n t gel which w o u l d be a good h a i r d r e s s i n g. The f o r m u l a i s a c l e a r ( m i c r o emulsion), " r i n g i n g " g e l. I_nar ed Le-nL s_ : A Mineral o i l A r l a s o l v e 200L I s o c e t e t h - E r i ] 93 O l e t h - 2
B Water Propylene g l y c o l Sorbitol Solution, Forestal1 W t% 11.0 27.8 6.0

5.0 7.0

Preparation Heat ( A ) and ( 8 ) t o 9OC. Add ( 8 ) t o ( A ) w i t h g e n t l e s t i r r i n g. Cool t o 8OC and a d d make-up w a t e r. S t i r u n t i l u n i f o r m and p o u r while s t i l l f l u i d. F o r m u l a HC- 1

O/W Lotion for Spray Application
Component: Wt% I. Emulgade SE/Glyceryl Stearate (and) Ceteareth-20 ( and 1 Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl 4.5 Palmitate 1.0 Eumulgin B2/Ceteareth-20 Cetiol LC/Coco-Caprylate/Caprate 5.0 Cetiol OE/Dicaprylyl Ether 5.0 II.Water, demin. 84.5 Preservative q.s Viscosity, 23C. mPas: t l O O Brookfield Preparation in the Laboratory: 1. Heat phase I to 85C and stir until homogeneous. 2. Heat phase I1 to 85C and stir slowly into phase I. 3. Allow the emulsion to cool with stirring; the stirring rate must be selected in such a way that the emulsion is kept in continual motion and no air is trapped. 4. Add preservative if necessary. Stop stirring at 30C. Formulation No. 93/060/24 Soft O/W Body Lotion Component: Wt% I. Emulgade SE/Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl 8.0 Palmitate 2.0 Eumulgin B 2/Ceteareth-20 2.0 Mandelol/Almond oil 2.0 Eutanol G/Octyldodecanol 8.0 Cetiol 868/0ctyl Stearate 55.0 I1.Water 5.0 Glycerin 86% 15.0 III.Carbopo2 % swelling/Carbomer 9.0 1V.NaOH (1% s o l ) q.s. Preservative Viscosity, mPas: 8000 Brookfield, 23C Preparation in the Laboratory: 1. Melt phase I at 85C and stir until homogeneous. 2. Melt phase I1 at 85C and stir slowly into phase I. Stir at temperature for min. 3. Allow the emulsion to cool until 50C with stirring and add phase 111. Stir until homogeneous. 4. Neutralize with phase IV. Allow to cool to 30C with stirring. Formulation No. 93/027/22
Oil-in-Water Stearic Acid Lotion A r l a c e l 165 p r o d u c e s a s t a b l e l o t i o n w h i c h i s made even more e l e g a n t by t h e a d d i t i o n o f A r l a m o l E. I n s r e d ients: W O A. S t e a r i c a c i d , t r i p l e pressed 2.0 t o 4.0 2.0 Arlamol E A r l a c e l 165 G l y c e r y l S t e a r a t e and PEG-100 S t e a r a t e 5.0 9. S o r b i t o l S o l u t ; o n , - U S P 10.0 Water 79.0 t o 81.0 Preservative q.s. Preparation: Heat ( A ) t o 70C. H e a t (9) t o 72C. Add ( B ) s l o w l y t o ( A ) w i t h r a p i d a g i t a t i o n. S t i r u n t i l c o o l e d t o room t e m p e r a t u r e. R e p l a c e w ater l o s t by e v a p o r a t i o n. F o r m u l a SK-2a Hand Lotion
Inaredi ent s : Wt% A. Light mineral o i l 8.0 3.0 Arlamol E 5.0 A r l a c e l 165 M y r j 52, PEG-40 S t e a r a t e 2.0 B r i j 30, L a u r e t h - 4 1. o 0. Water 76.4 4.0 S o r b i t o l S o l u t i o n , USP Carbomer 934 0.3 C. Sodium h y d r o x i d e s o l u t i o n , 10% aqueous 0.3 D. Preservative q.s. P r e p a r a t io n : D i s p e r s e Carbomer 934 w i t h a g i t a t i o n and h e a t t o 72C. H e a t ( A ) t o 70C. Add ( B ) t o ( A ) w i t h m o d e r a t e a g i t a t i o n. Add ( C ). Add ( D ) b e l o w C. S t i r t o 35C and r e p l a c e w a t e r l o s t b y evaporation. F o r m u l a SK-3

Cosmetic and Tolefry Formulations
Ultra-AHA Moisturizing Skin Lotion Formula P r o f i l e : The s y n e r g i s t i c m i x t u r e o f Veegum U l t r a and R h o d i g e l w i l l c r e a t e an AHA cream t h a t w i l l have g r e a t s p r e a d i b i l i t y and f e e l w i t h o u t t h e t a c k and s t r i n g i n e s s c h a r a c t e r i s t i c o f R h o d i g e l. Veegum U l t r a w i l l i m p r o v e s t a b i l i t y and m a i n t a i n t h e v i s c o s i t y o f t h e p r o d u c t. The e m o l l i e n t s i n t h e o i l phase and t h e humecta n t s i n t h e w a t e r phase w i l l p r o v i d e r e s i d u a l s k i n f e e l and moi s t u r i z a t i o n. Wt% InQredients: 73 I A : Water 1.5 Veegum U l t r a (Magnesium Aluminum S i l i c a t e ) R h o d i g e l ( X a n t h a n Gum) 0.5 6: Glycerin 3.0 B u t y l e n e G1 y c o l 2.0 C: Cetyl Alcohol 1* o G l y c e r y l M o n o s t e a r a t e SE ( D e r m a c a r e MS SE) 3.0 5.0 C a p r y l i c / C a p r i c T r i g l y c e r i d e (Neobee M-5) C12-15 O c t a n o a t e ( F i n e s t e r EH-25) 1.o D i m e t h i c o n e (DC-200 f l u i d - 0 c t s ) 1.o Steareth-2 ( B r i j 72) 0.83 0.83 S t e a r e t h - ( B r i j 721) D: Preservative qs E: Glycolic Acid 7.0 F: Fragrance qs G: T r i e t h a n o l a m i n e 3.2 qs C i t r i c Acid A d j u s t pH t o 3. - 0. 2 Procedure: S t e p 1 : D r y b l e n d Veegum U l t r a and R h o d i g e l i n P a r t A. ( D r y b l e n d i n g r e d u c e s t h e c l u m p i n g o f R h o d i g e l and a l l o w s f o r t h e s i m u l t a n e o u s i n t r o d u c t i o n o f i n g r e d i e n t s ). S i f t t h e powder i n t o an e s t a b l i s h e d v o r t e x i n t h e w a t e r. Veegum U l t r a w i l l be h y d r a t e d w i t h i n 15 m i n u t e s. A l l o w a b o u t 45 m i n u t e s f o r R h o d i g e l t o dissolve completely. The a d d i t i o n o f any o t h e r i n g r e d i e n t s d u r i n g t h e h y d r a t i o n p r o c e s s w i l l i n t e r f e r e w i t h t h e h y d r a t i o n o f Veegum U l t r a and w i l l r e d u c e o r even e l i m i n a t e t h e d e s i r e d p r o p e r t i e s g e n e r a t e d b y t h e Magnesium Aluminum S i l i c a t e. S t e p 2 : B e g i n h e a t i n g w a t e r phase i n S t e p 1 t o 75C. S t e p 3 : Once t h e h y d r a t i o n p r o c e s s i s c o m p l e t e d , add r e m a i n i n g w a t e r phase i n g r e d i e n t s f rom P a r t B t o St ep 2. S t e p 4 : B l e n d o i l phase i n g r e d i e n t s i n Phase C and h e a t t h e o i l p h a s e t o 75C. S t e p 5 : When b o t h p h a s e s a r e a t 75C, add o i l phase i n S t e p 4 t o w a t e r phase S t e p 2 , S t e p 6 : C o o l t o 45C. Add P a r t D - P r e s e r v a t i v e t o S t e p 2. S t e p 7 : Add P a r t E - A H A - G l y c o l i c A c i d t o S t e p 2. S t e p 8 : Add P a r t F - F r a g r a n c e t o S t e p 2. S t e p 9 : Cool t o 35C. A d j u s t pH w i t h P a r t G. Product S p e c i f i c a t i o n s : V i s c o s i t y : B r o o k f i e l d LVT: , 0 + - , 0 c p s a f t e r 24 h o u r s pH\ 3.6-4.0 T h i s f o r m u l a produces a s t a b l e emulsion-passes 3 month t e s t i n g SOURCE: R. T. V a n d e r b i l t C o. , I n c. : F o r m u l a No. 476

76.9 0.2

12.5 0.6 0.1 1.6 5.0 0.5 0.2 0.2 2.0
Procedure: D i s p e r s e and d i s s o l v e t h e carbomer 4 i n t h e w a t e r. Add t h e J o r d a p o n C I - F l a k e , f a t t y a c i d s a n d p a r a f f i n , h e a t i n g t o 55C ( 0 F ) t o d i s s o l v e. P r e m i x t h e p r o p y l e n e g l y c o l , PEG-75 l a n o l i n , p r e s e r v a t i v e , a n d f r a g r a n c e ; a d d t o t h e b a t c h. A d j u s t pH t o 7. 0 - 7. 5 w i t h t r i e t h a n o l a m i n e. Use t h i s c o n c e n t r a t e a t 96% w i t h 4% P r o p e l l a n t A-46. Foamul a t ion P-301

Electric Preshave

A h y d r o - a l c o h o l i c s p l a s h w h i c h l u b r i c a t e s t h e s k i n and w e t s t h e b e a r d f o r a f a s t e r , more c o m f o r t a b l e s h a v e. The f o r m u a a l s o w o r k s w e l l a s a m o i s t u r i z i n g a f t e r s h a v e , and a s a m o i s t u r z i n g a f t e r b a t h splash.
Lng c e d is^ t_/Lrsde_N_a_m_e_: PPG-10 B u t a n e d i o l / M a c o l 57 D i m e t h i c o n e C o p o l y o l / M a s i l 260 Fragrance SD A l c o h o l 8 D e i on1 z e d Water Appearance: C l e a r , w a t e r - w h i t e
3.0 0.5 Q.S. 25.0 71.5 fluid
Procedure: Blend t h e f i r s t t h r e e i n g r e d i e n t s a t ambient temperature. Add t h e f r a g r a n c e , a n d b l e n d u n t i l u n i f o r m. Add t h e w a t e r , a n d blend u n t i l uniform. Formu 1a t io n P- 4
Shave Gel F o r m u l a t i n g Desi gn and A d v a n t a g e s : The p r o d u c t w i l l r a i s e t h e h a i r o f f t h e f a c e t o make f o r a c l o s e r c u t w i t h o u t i r r i t a t i o n. The H e x a n e d i o l B e h e n y l Beeswax s t a b i l i z e s t h e s i l i c o n e o i l t o l e a v e t h e s k i n s i l k y and s m o o t h. Raw M a t e r ia1 s : Phase A : Hexanedi o l B e h e n y l Beeswax D e o d o r i z e d Orange Wax P e r m e t h y l 104A Polybutene Isostearic Acid Palmitic Acid Phase B : P u r i f i e d Water Triethanolamine C a r b o p o l 0 (2% d i s p e r s i o n ) A l o e V e r a Gel A1 l a n t o i n Germaben I 1 Phase C : S i 1i c o n e 345

W % ~ t_ _

3.0 2.0 3.0 4.0 0.6 1.4 63.9 0.8 12.0 0.8 0.8 1.o 6.7
Procedure: Heat and m i x Phase A and add t o a h e a t e d and m i x e d Phase B. Cool t o 50C and a d d Phase C. Cool t o 40C and p o u r. A d a p t a t i o n o f F o r m u l a and i t s I n f l u e n c e on t h e P r o d u c t : F r a g r a n c e s , a c t i v e s and o t h e r s i l i c o n e o i l s can be i n c o r p o r a t e d i n t o t h i s t y p e o f f o r m u l a , w i t h o n l y m i n i m a l changes i n s t a b i l i t y and p e r f o r m a n c e.

Procedure: 1. Dissolve cetyl alcohol and deionized water at 8OC with stirring. 2. Add titanium dioxide and EDTA disodium salt and disperse thoroughly. 3. Add small amount of GS-11 (39 per 1009 of water) to the mixture to emulsify at 8OC, with continued stirring. 4. Add the mixture from step 3 to GS-11 and Sodium cocoylisethionate and mingle thoroughly. 5. Mill the mixture on a roller mill and then convert into a bar through an extruder. 6. Mold the bar in a stamping machine. Formula AI-KK SOURCE: Ajinomoto U.S.A., Inc.: Suggested Formulations
Cosmetic and Toiletry Formdations
D-Limonene Hand Cleaner An opaque, f i r m g e l w a t e r l e s s hand c l e a n e r b a s e d o n n a t u r a l d-1 imonene a n d b i o d e g r a d a b l e emu1 s i f i e r s. E f f e c t i v e , c l e a n r i n s i n g , and p l e a s a n t - s m e l l i n g. W B Part: I n n r e d i e n t / T r a d e Name: A d-Limonene, Grade M 0 B u t y l a t e d H y d r o x y T o l u e n e (BHT) 0.1 e i c A c i d/Pamol yn 125 7.20 Cocamide DEA/Mazamide JT-128 1.70 5.00 P o l y s o r b a t e 80/T-Maz 0.50 PEG-85 L a n o l in / L a n o g e l 65 B Triethanolamine 3.10 G1 y c e r i n 1.oo D e i o n i z e d Water 61.39 Na4EDTA 0.01 pH: 8. 2 - 8. 5 Odor: C i t r u s A p p e a r a n c e : W h i t e , opaque g e l Procedure: No h e a t i n g i s r e q u i r e d t o p r o c e s s t h i s f o r m u l a. I n a s i d e v e s s e l , d i s s o l v e t h e BHT i n t h e d-Limonene, t h e n b l e n d i n t h e o t h e r p a r t A i n g r e d i e n t s. I n t h e main v e s s e l , b l e n d t h e p a r t B i n g r e d i e n t s. W i t h r a p i d p r o p e l l o r m i x i n g , add p a r t A t o p a r t B, f o r m i n g t h e e m u l s i o n. Check a n d a d j u s t pH, t h e n p a c k a g e. P r o d u c t i s a f l o w a b l e l i q u i d when made, t h i c k e n s t o a s o f t cream i n a b o u t 2 h o u r s , a n d becomes a r i n g i n g g e l i n a b o u t 3 h o u r s. F o r m u l a t i o n 0-1 06
Waterless Hand Cleaner with d-Limonene A f i r m w h i t e cream f o r h e a v y - d u t y h a n d c l e a n i n g w i t h o r w i t h o u t w a t e r. The d - l i m o n e n e a i d s g r e a s e - c u t t i n g i n a d d i t i o n t o f r a g r a n c i n g t h e p r o d u c t. M a z c l e a n EP p r o v i d e s e m u l s i f i c a t i o n ane d e t e r g e n c y a s w e l l a s i m p r o v e d r i n s a b i l i t y , _ _d i e n t / T r a d e I n.r e g Name: ye, Part: 25.00 A D e o d o r i z e d Kerosene 5.00 L i g h t M i n e r a l O i 1/Drake5.00 d - L i m o n e n e , Grade M d-Limonene E m u l s i f i e r / M a z c l e a n EP 6.00 5.00 S t e a r i c A c i d / H y s t r e n e 5016 49.83 B Water 2.00 G1 y c e r i n 2.10 T r i e t h a n o l a m i n e , 99% 0.07 P r e s e r v a t i v e / K a t h o n CG pH: 7. 5 - 8. 0 V i s c o s i t y : 550,000-600,000 c p s ( B r o o k f i e l d TD @ 0. 3 rpm) A p p e a r a n c e : F i r m , g l o s s y w h i t e cream Procedure: B l e n d t h e P a r t A i n g r e d i e n t s i n t h e m a i n v e s s e l , h e a t t o 60C. I n a second v e s s e l , b l e n d and h e a t t h e P a r t B i n g r e d i e n t s t o 60C. S l o w l y a d d P a r t B t o A w i t h good a g i t a t i o n. The b a t c h w i l l t h i c k en a s t h e e m u l s i o n f o r m s , t h e n i t w i l l t h i n s l i g h t l y a s t h e e m u l s i o n i n v e r t s. C o o l t h e b a t c h t o 35C w i t h sweep s t i r r i n g t i p a c k o f f. F o r m u l a t i o n 0-SOURCE: PPG I n d u s t r i e s , I n c. : S u g g e s t e d F o r m u l a t i o n s

R.T. Vanderbilt Co., Inc.
I n c. : F o r m u l a t i o n from P r e s p e r s e ,

Sunscreen Formulation

_.r Inq
e d ients; Veegum P l u s D e i o n i z e d Water Triethanolamine P r o p y l e n e G1 y c o l E m u l s i f y i n g Wax NF Stearic Acid PPG-2 M y r i s t y l E t h e r P r o p i o n a t e Cetyl Alcohol Lanolin Alcohol Padimate 0 Phenylbenzimidazole S u l f o n i c A c i d Preservative B r o o k f i e l d V i s c o s i t y @ rpm, c p s : A f t e r A g i n g 1 Day: 19500 A f t e r A g i n g 1 Week: 19500 A f t e r A g i n g 4 Weeks: 21500 Y i e l d Value, Dynes/Sq. C m. : 1020
W t.% 2.00 61.50 0.80 5.00 3.20 2.40 11.20

1.60 4.00 5.00 2.30

F o r m u l a pH: A f t e r A g i n g 1 Day: 6. 6 A f t e r A g i n g 1 Week: 6. 5 A f t e r A g i n g 4 Weeks: 6. 5 S t a b i l i t y Observations: A f t e r A g i n g 1 Week @ Room T e m p. : OK A f t e r A g i n g 4 Weeks @ Room T e m p. : O K A f t e r A g i n g 1 Week @ 6C: A f t e r A g i n g 4 Weeks @ 6 C :
A f t e r A g i n g 1 Week @ 38C: OK A f t e r A g i n g 4 Weeks I3 38C: OK A f t e r A g i n g 1 Week @ 50C: OK 3 A f t e r A g i n g 4 Weeks I 50C: OK
R. T. V a n d e r b i l t Co.,
I n c. : Suggested F o r m u l a t i o n
Sunscreen Formulation Inqredients:

MAS Type 1A

2.00 61.50 0.80 5.00 3.20
Deionized Water Triethanolamine Propylene Glycol Emulsifying Agent NF Stearic Acid PPG-2 Myristyl Ether Propionate Cetyl Alcohol Lanolin Alcohol Padimate 0 Phenylbenzimidazole Sulfonic Acid Preservative
Brookfield Viscosity @ 12 rpm, cps: After Aging 1 Day: 11500 After Aging 1 Weeks: 10500 After Aging 4 Weeks: 13500 Yield Value, Dynes/Sg. Cm.: 600 Formula pH: After Aging 1 Day: 6.6 After Aging 1 Week: 6.6 After Aging 4 Weeks: 6.6 Stability Observations: After Aging 1 Week @ Room Temp.: OK After Aging 4 Weeks @ Room Temp.: OK
11.20 1.60 4.00 5.00 2.30 1.00
After Aging 1 Week @ 6C: OK After Aging 4 Weeks @ 6C: OX After Aging 1 Week @ 38C: OK After Aging 4 Weeks @ 38C: Trace Bleed After Aging 1 Week @ 50C: 5 m Bleed After Aging 4 Weeks @ 50C: Total Separation
SOURCE: R.T. Vanderbilt Co., Inc.: Formulation
Sunscreen Gel F o r m u l a t i n g D e s i g n and A d v a n t a g e s : Cera B e l l i n a (Pg-3 Beeswax) p r o d u c e s a n o n - g r a n u l a r , l o w p e n e t r a t i o n and h i g h s t a b i l i t y g e l. T h i s f o r m u l a u t i l i z e s an a r r a y o f o i l s and a c t i v e s p r o d u c i n g a p r o d u c t w i t h a n o n - g r e a s y s k i n f e e l , p e n e t r a t e s t h e s k i n q u i c k l y and has an SPF o f 4 t o 6.